Basic information Safety Supplier Related

1-BOC-2-BENZYL-PIPERIDIN-4-ONE

Basic information Safety Supplier Related

1-BOC-2-BENZYL-PIPERIDIN-4-ONE Basic information

Product Name:
1-BOC-2-BENZYL-PIPERIDIN-4-ONE
Synonyms:
  • 1-BOC-2-BENZYL-PIPERIDIN-4-ONE
  • 1-N-BOC-2-BENZYL-PIPERIDIN-4-ONE
  • 1-Piperidinecarboxylicacid,4-oxo-2-(phenylMethyl)-,1,1-diMethylethylester
  • 1-Boc-2-Benzyl-4-piperidine
  • 1-Boc-2-Benzyl-4-piperidinone
  • 4-oxo-2-(phenylmethyl)-1-piperidinecarboxylic acid tert-butyl ester
CAS:
193480-28-3
MF:
C17H23NO3
MW:
289.37
EINECS:
200-589-5
Product Categories:
  • Piperidine
  • Piperidines
Mol File:
193480-28-3.mol
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1-BOC-2-BENZYL-PIPERIDIN-4-ONE Chemical Properties

Melting point:
79-80o C
Boiling point:
409.0±38.0 °C(Predicted)
Density 
1.115±0.06 g/cm3(Predicted)
storage temp. 
2-8°C
solubility 
DMSO (Slightly), Methanol (Slightly)
form 
Solid
pka
-1.58±0.40(Predicted)
color 
White to Off-White
CAS DataBase Reference
193480-28-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-51
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1-BOC-2-BENZYL-PIPERIDIN-4-ONE Usage And Synthesis

Synthesis

193469-44-2

34619-03-9

193480-28-3

2-Benzylpiperidin-4-one (17 g) and di-tert-butyl carbonate (21.8 g) were mixed in dichloromethane (500 ml). The reaction mixture was stirred at room temperature for 48 hours. After completion of the reaction, the solvent was removed by rotary evaporation. The organic layer was separated by dissolving the residue in water and toluene. The aqueous layer was extracted again with toluene. All organic layers were combined, dried with anhydrous sodium sulfate, filtered and concentrated to give 38 g (100% yield) of (±)-1-tert-butoxycarbonyl-2-benzyl-4-piperidone (Intermediate 6).

References

[1] Patent: US6346540, 2002, B1. Location in patent: Page column 17

1-BOC-2-BENZYL-PIPERIDIN-4-ONESupplier

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