Basic information Reaction Safety Supplier Related

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)

Basic information Reaction Safety Supplier Related

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Basic information

Product Name:
Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
Synonyms:
  • CHLORO(2-METHYLPHENYL)(N,N,N',N'-TETRAMETHYL-1,2-ETHYLENEDIAMINE)NICKEL(II),99%(CONTAINSABOUT5%O-CHLOROTOLUENE)NICL(O-TOLYL)(TMEDA)
  • Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II), 99% (contains about 10% o-chlorotoluene) NiCl(o-tolyl)(TMEDA)
  • Nicl(O-Tolyl)(Tmeda)
  • Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)
  • chloro(2-methylphenyl)(N,N,N`,N`-tetramethyl-1,2-ethylenediamine)nickel
  • Chloro(2-methylphenyl)(N,N,N'',N''-tetramethyl-1,2-ethylenediamine)nickel(II)
CAS:
1702744-45-3
MF:
C13H23ClN2Ni
MW:
301.48152
Mol File:
1702744-45-3.mol
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Chemical Properties

form 
Powder
color 
dark-orange
Sensitive 
air sensitive
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Safety Information

Risk Statements 
45-42/43
Safety Statements 
53-22-36/37/39-45
TSCA 
No
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Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II) Usage And Synthesis

Reaction

  1. Air-Stable Nickel precatalyst for cross-coupling
  2. Precatalyst allowing various ligands to be used (monoand bidendate phosphines, diimines and NHCs)

Uses

Effective precatalyst for a variety of nickel-catalyzed transformations, including Suzuki-Miyaura, Buchwald-Hartwig and other cyclizations and oxidative couplings.

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

Chloro(2-methylphenyl)(N,N,N',N'-tetramethyl-1,2-ethylenediamine)nickel(II)Supplier

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