CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE Chemical Properties

Melting point:

136-138 °C(lit.)

storage temp. 

Inert atmosphere,Room Temperature

solubility 

a suspension in THF, DME, DMSO, MeCN

form 

powder to crystal

color 

White to Almost white

BRN 

4172245

InChI

InChI=1S/C15H15S.BF4/c1-3-7-13(8-4-1)16(15-11-12-15)14-9-5-2-6-10-14;2-1(3,4)5/h1-10,15H,11-12H2;/q+1;-1

InChIKey

DWEYKSWKFYZEGZ-UHFFFAOYSA-N

SMILES

[S+](C1C=CC=CC=1)(C1=CC=CC=C1)C1CC1.[B-](F)(F)(F)F

CAS DataBase Reference

33462-81-6(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi

Risk Statements 

36/37/38

Safety Statements 

26-36

RIDADR 

1759

WGK Germany 

3

Hazard Note 

Irritant

HazardClass 

8

PackingGroup 

III

HS Code 

2931900090

MSDS

• Language:English Provider:ACROS
• Language:English Provider:SigmaAldrich

CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE Usage And Synthesis

Chemical Properties

WHITE FINE CRYSTALLINE POWDER

Uses

CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE is used as a versatile C3 building block; reagent for the spiroannulation of carbonyl compounds.

Synthesis

Cyclopropyldiphenylsulfonium Tetrafluoroborate's synthesis:

References

[1] Journal of Organic Chemistry, 2009, vol. 74, # 3, p. 1304 - 1313
[2] Patent: WO2017/83867, 2017, A1. Location in patent: Paragraph 00272; 00273
[3] Journal of the American Chemical Society, 1973, vol. 95, p. 5298 - 5307

CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE(33462-81-6)Related Product Information

• DIPHENYL(METHYL)SULFONIUM TETRAFLUOROBORATE
• DIPHENYL(ETHYL)SULPHONIUM TETRAFLUOROBORATE, 97
• CYCLOPROPYL PHENYL SULFIDE
• CYCLOPROPYLDIPHENYLSULFONIUM TETRAFLUOROBORATE
• TRIMETHYLSULFONIUM TETRAFLUOROBORATE
• Diphenyl sulfide
• BORON TRIFLUORIDE-METHANOL
• PHENYL N-PROPYL SULPHIDE
• ISOPROPYLTHIOBENZENE
• Fluoroboric acid
• Borane-methyl sulfide complex