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Gentiopicroside

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Gentiopicroside Basic information

Product Name:
Gentiopicroside
Synonyms:
  • 1H,3H-Pyrano[3,4-c]pyran-1-one,5-ethenyl-6-(β-D-
  • glucopyranosyloxy)-5,6-dihydro-,(5R-trans)-
  • (5R,6S)-5-ethenyl-6-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-5,6-dihydro-3H-pyrano[5,4-c]pyran-1-one
  • 1H,3H-Pyrano[3,4-c]pyran-1-one, 5-ethenyl-6-(b-D-glucopyranosyloxy)-5,6-dihydro-, (5R,6S)-
  • 1H,3H-Pyrano[3,4-c]pyran-1-one, 5-ethenyl-6-(b-D-glucopyranosyloxy)-5,6-dihydro-, (5R-trans)-
  • (5R)-5β-Ethenyl-6α-(β-D-glucopyranosyloxy)-5,6-dihydro-1H,3H-pyrano[3,4-c]pyran-1-one
  • (5R)-5β-Vinyl-6α-(β-D-glucopyranosyloxy)-5,6-dihydro-1H,3H-pyrano[3,4-c]pyran-1-one
  • GENTIOPICRIN
CAS:
20831-76-9
MF:
C16H20O9
MW:
356.33
EINECS:
244-070-2
Product Categories:
  • Inhibitors
  • chemical reagent
  • pharmaceutical intermediate
  • phytochemical
  • reference standards from Chinese medicinal herbs (TCM).
  • standardized herbal extract
  • Iridoids
Mol File:
20831-76-9.mol
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Gentiopicroside Chemical Properties

Melting point:
191°C
alpha 
-200 º (c=2, H2O)
Boiling point:
667.8±55.0 °C(Predicted)
Density 
1.52±0.1 g/cm3(Predicted)
storage temp. 
2-8°C(protect from light)
solubility 
DMSO (Slightly), Ethanol (Slightly, Sonicated)
form 
Solid
pka
12.79±0.70(Predicted)
color 
Pale Beige
biological source
plant (Gentiana macrophylla Pall)
optical activity
[α]/D -185 to -205°, c =1 in H2O
Water Solubility 
H2O: 20mg/mL, clear
Stability:
Hygroscopic
LogP
-3.170 (est)
CAS DataBase Reference
20831-76-9(CAS DataBase Reference)
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Safety Information

HS Code 
29389090

MSDS

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Gentiopicroside Usage And Synthesis

Chemical Properties

Off-white crystalline powder, easily soluble in methanol, almost insoluble in ether, derived from Gentiana longipedalis (Tibet, Gansu) Gentiana rhizome, Gentiana scabra.

Uses

Gentiopicroside is an anticonvulsant agent present in plant extracts.

Definition

ChEBI: Gentiopicrin is a glycoside.

Biological Activity

Gentiopicroside is an important active component of secoiridoid glycosides from Gentiana macrophylla Pall th at exhibit anti-inflammatory, antibacterial and liver protecting activities. Gentiopicroside protects chondrocytes from IL-1β-induced inflammation response.', 'Gentiopicroside possesses analgesic, anti proliferative, wound healing and antioxidant properties (free radical scavenging activity). Gentiopicroside shows low oral bioavailability, hence it establishes its therapeutic action after metabolism.

in vivo

Gentiopicroside (20, 40, and 80 mg/kg, p.o.) significantly reduces gastric ulcerindex in mice. Gentiopicroside (20, 40, and 80 mg/kg) also ovbiously decreases the levels of HSP-70, TNF-α, IL-6, MDA and increases ncreased GSH level and SOD activity. In addition, Gentiopicroside normalizes EGF and VEGF level in mice[2].

IC 50

CYP2

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