Triisopropylsilane
Triisopropylsilane Basic information
- Product Name:
- Triisopropylsilane
- Synonyms:
-
- Triisopropylsilane(L)
- Three isopropylsilane
- Triisopropylsilane 99%
- Triisopropylsilane Synonyms Triisopropylhydrosilane
- HandyStep
- PD-Tips
- tris(propan-2-yl)silane
- Triisopropylsilane, 98% 10GR
- CAS:
- 6485-79-6
- MF:
- C9H22Si
- MW:
- 158.36
- EINECS:
- 464-880-1
- Product Categories:
-
- Chemical Synthesis
- Organometallic Reagents
- Other Reagents
- Reduction
- Others
- Synthetic Reagents
- Si (Classes of Silicon Compounds)
- Si-H Compounds
- Silicon Compounds (for Synthesis)
- Synthetic Organic Chemistry
- Alkyl Silanes
- Hydrogensilanes Hydrogensiloxanes
- Reducing Agents
- Biochemics
- Organometallic Reagents
- Organosilicon
- OthersSynthetic Reagents
- Silanes
- bc0001
- Mol File:
- 6485-79-6.mol
Triisopropylsilane Chemical Properties
- Boiling point:
- 84-86 °C/35 mmHg (lit.)
- Density
- 0.773 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.434(lit.)
- Flash point:
- 99 °F
- storage temp.
- Store below +30°C.
- solubility
- Benzene (Soluble), Chloroform (Soluble)
- form
- liquid
- Specific Gravity
- 0.773
- color
- colorless
- Water Solubility
- Immiscible with water.
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- BRN
- 1733718
- InChIKey
- YDJXDYKQMRNUSA-UHFFFAOYSA-N
- CAS DataBase Reference
- 6485-79-6(CAS DataBase Reference)
Safety Information
- Hazard Codes
- Xi
- Risk Statements
- 10-36/37/38
- Safety Statements
- 26-36-37/39-16
- RIDADR
- UN 1993 3/PG 3
- WGK Germany
- 3
- F
- 10-21
- TSCA
- No
- HS Code
- 2931 90 00
- HazardClass
- 3
- PackingGroup
- III
MSDS
- Language:English Provider:SigmaAldrich
- Language:English Provider:ACROS
- Language:English Provider:ALFA
Triisopropylsilane Usage And Synthesis
Chemical Properties
Clear colorless liquid
Uses
The bulky isopropyl groups (vs. ethyl) allow for more selective reductions, e.g., beta-selective reduction of anomeric C-phenyl ketals, but do not diminish their activity (e.g. in the copper triflate catalyzed reductive etherification of trimethylsilyl ethers).
Uses
Selective silylation of primary hydroxy groups in the presence of secondary alcohol.
Uses
Triisopropylsilane is used as a protecting group in peptide synthesis and is also used as a reducing agent for the selective reduction of anomeric C-phenyl ketals. It is used in the selective silylation of primary hydroxyl groups without affecting the secondary hydroxyl group. It is used in the preparation of anti-1,2-diols catalyzed by a Ni(O) N-heterocyclic carbine complex with high diastereoselectivity.
Application
Very sterically-hindered silane. Used as a cation scavenger in the deprotection of peptides.
TriisopropylsilaneSupplier
- Tel
- 021-69106960 13701823733
- 13701823733@163.com
- Tel
- 18936270273
- upkind@upkind.com
- Tel
- 021-61530618
- sales@chuqingtech.com
- Tel
- 17312398916
- sales@zhuangming.net
- Tel
- 0571-87225286 18966162194
- 578958341@qq.com
Triisopropylsilane(6485-79-6)Related Product Information
- 3-Chloropropyltrimethoxysilane
- 3-Aminopropyltrimethoxysilane
- Trimethoxypropylsilane
- N-Methyl-2-pyrrolidone
- Triethoxypropylsilane
- Trimethoxysilylpropanethiol
- 3-Mercaptopropyltriethoxysilane
- Triisopropylsilyl chloride
- ISOPROPYLTRICHLOROSILANE
- Isoproterenol
- N,N-Diisopropylethylamine
- Triethoxyvinylsilane
- (TRIISOPROPYLSILYL)ACETYLENE
- TRIISOPROPOXYSILANE
- Chlorotriethylsilane
- Triethylsilane
- Triisopropyl phosphite
- Triisopropyl borate