Basic information Reaction Safety Supplier Related

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)

Basic information Reaction Safety Supplier Related

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Basic information

Product Name:
Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
Synonyms:
  • Carbonylchlorohydrido[6-(di-t-butylphosphinoMethyl)-2-(N,N-diethylaMinoMethyl)pyridine]rutheniuM(II),98% (Milstein Catalyst Precursor)
  • [2-(Di-tert-butylphosphinoMethyl)-6-(diethylaMinoMethyl)pyridine]carbonylchlorohydridorutheniuM(II)
  • Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)
    pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)
  • Carbonylchlorohydrido[6-(di-tert-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II)
  • [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
  • Milstein Catalyst Precursor
  • Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98%
CAS:
863971-62-4
MF:
C20H37ClN2OPRu
MW:
489.02
Product Categories:
  • Ru
  • organometallic complex
Mol File:
863971-62-4.mol
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Chemical Properties

storage temp. 
under inert gas (nitrogen or Argon) at 2-8°C
form 
solid
color 
pale yellow
Sensitive 
air sensitive
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Safety Information

Hazard Codes 
Xn
Risk Statements 
19-40
Safety Statements 
36/37
WGK Germany 
3
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor) Usage And Synthesis

Reaction

  1. Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
  2. Ruthenium catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
  3. Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
  4. Ruthenium catalyst for the synthesis of amides from esters and amines with liberation of hydrogen gas.
  5. Ruthenium catalyst for the hydrogenation of 3-methyl-2-oxalidinone

Uses

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

General Description

May contain up to 10% acetone and/or THF.

Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)Supplier

Nanchang Zhenshi Biotechnology Co., Ltd Gold
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18679828511
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408289529@qq.com
J & K SCIENTIFIC LTD.
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010-82848833 400-666-7788
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Energy Chemical
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021-021-58432009 400-005-6266
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Beijing Guofang Dingsheng Technology Co., Ltd.
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18610472091 18610472091
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gfdskj@163.com
Sigma-Aldrich
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021-61415566 800-8193336
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orderCN@merckgroup.com
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Carbonylchlorohydrido[6-(di-t-butylphosphinomethyl)-2-(N,N-diethylaminomethyl)pyridine]ruthenium(II), min. 98% (Milstein Catalyst Precursor)(863971-62-4)Related Product Information