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MERCUROUS NITRATE

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MERCUROUS NITRATE Basic information

Product Name:
MERCUROUS NITRATE
Synonyms:
  • MERCUROUS NITRATE
  • MERCURY (I) NITRATE
  • MERCUY NITRATE
  • MERCURY(I) NITRATE DIHYDRATE, REAGENT G&
  • MERCURY (I) NITRATE DIHYDRATE ACS 98+%
  • Mercury(I) nitrate hydrate (ACS)
  • Mercury(I)nitratemonohydrate,98+%(ACS)
  • Nitric acid, mercury(1+) salt, monohydrate
CAS:
7782-86-7
MF:
H3HgNO4
MW:
281.62
EINECS:
233-886-4
Product Categories:
  • metal nitrate salts
Mol File:
7782-86-7.mol
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MERCUROUS NITRATE Chemical Properties

Melting point:
70°C
Density 
4.78 g/mL at 25 °C(lit.)
storage temp. 
Poison room
Water Solubility 
Slightly soluble in water.
solubility 
insol alcohol, ether; sol H2O containing 1% HNO3 (with H2O alone, basic salt is formed).
form 
Powder/Solid
Specific Gravity
4.79
color 
White to yellow
Stability:
Stable, but may be sensitive to light or moisture. Strong oxidizer. Incompatible with combustible materials, reducing agents.
CAS DataBase Reference
7782-86-7(CAS DataBase Reference)
EPA Substance Registry System
Mercurous nitrate, monohydrate (7782-86-7)
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Safety Information

Hazard Codes 
T+,N
Risk Statements 
26/27/28-33-50/53
Safety Statements 
13-28-45-60-61
RIDADR 
UN 1627 6.1/PG 2
WGK Germany 
3
HS Code 
28521000
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MERCUROUS NITRATE Usage And Synthesis

Chemical Properties

Mercurous nitrate,HgN03•2H20, is colorless,efflorescent, light-sensitive crystals that decompose in water,and melt at 70℃. Also known as hydrated mercurous nitrate, it is highly toxic and explosive if shocked or heated and is used as an analytical agent.

Uses

Mercurous nitrate can be used to synthesize alkyl nitrates from alkyl halides.

storage

Acute poison. Exposure to all mercury compounds is to  be strictly avoided. Releases toxic Hg fumes when heated to decomposition. Protect from  light.

Purification Methods

Its solubility in H2O containing 1% HNO3 is 7.7%. Recrystallise it from a warm saturated solution of dilute HNO3 and cool to room temperature slowly to give elongated prisms. Rapid cooling gives plates. The colourless crystals should be stored in the dark. POISONOUS. [Grdenic J Chem Soc 1312 1956.]

MERCUROUS NITRATESupplier

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