Basic information Safety Supplier Related

Rhodium (III) chloride trihydrate

Basic information Safety Supplier Related

Rhodium (III) chloride trihydrate Basic information

Product Name:
Rhodium (III) chloride trihydrate
Synonyms:
  • RHODIUM TRICHLORIDE, HYDRATE
  • RHODIUM TRICHLORIDE TRIHYDRATE
  • RHODIUM CHLORIDE
  • RHODIUM CHLORIDE, HYDROUS
  • RHODIUM CHLORIDE TRIHYDRATE
  • Rhodium (III) chloride solution
  • RHODIUM(III) CHLORIDE-3-HYDRATE PACKAGE&
  • RhodiumTrichlorideForSynthesis
CAS:
13569-65-8
MF:
Cl3H6O3Rh
MW:
263.31
EINECS:
682-140-8
Mol File:
13569-65-8.mol
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Rhodium (III) chloride trihydrate Chemical Properties

Melting point:
100 °C (decomp)
Density 
1 g/cm3
storage temp. 
Sealed in dry,Room Temperature
CAS DataBase Reference
13569-65-8(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xn
Risk Statements 
22-41
Safety Statements 
26-36/39
RIDADR 
3260
WGK Germany 
WGK 1 slightly water endangering
HazardClass 
8
PackingGroup 
III
HS Code 
28439090
Toxicity
LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg

MSDS

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Rhodium (III) chloride trihydrate Usage And Synthesis

Description

Rhodium trichloride is an odourless, red-brown to black crystalline powder. It is corrosive to steel and aluminium. It is hygroscopic and absorbs moisture or water from the air. It is incompatible with strong oxidising agents. On decomposition, rhodium trichloride emits hydrogen chloride, carbon monoxide, carbon dioxide, and rhodium/rhodium oxides.

Chemical Properties

Rhodium trichloride is a red-brown or black, odorless solid or liquid

Potential Exposure

Rhodium trichloride is used in hydro- silylation, hydrogenation, carbonylation, oxidation, aryla- tion. See also “Rhodium Metal.” In plating operations and in catalyst preparation, the metal will be used as the trichloride.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

Sensitive to humidity. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materi- als, strong bases, strong acids, oxoacids, and epoxides.

Waste Disposal

Recovery and reclaiming wherever possible in view of high economic value. See “Rhodium Metal.”

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