Rhodium (III) chloride trihydrate Chemical Properties

Melting point:

100 °C (decomp)

Density 

1 g/cm3

storage temp. 

Sealed in dry,Room Temperature

Appearance

Reddish brown to black Solid

InChI

InChI=1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3

InChIKey

HSSMNYDDDSNUKH-UHFFFAOYSA-K

SMILES

[Rh](Cl)(Cl)Cl.O

CAS DataBase Reference

13569-65-8(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xn

Risk Statements 

22-41

Safety Statements 

26-36/39

RIDADR 

3260

WGK Germany 

WGK 1 slightly water endangering

HazardClass 

8

PackingGroup 

III

HS Code 

28439090

Toxicity

LD50 orally in Rabbit: 753 mg/kg LD50 dermal Rabbit > 2000 mg/kg

MSDS

• Language:English Provider:Rhodium chloride trihydrate

Rhodium (III) chloride trihydrate Usage And Synthesis

Description

Rhodium trichloride is an odourless, red-brown to black crystalline powder. It is corrosive to steel and aluminium. It is hygroscopic and absorbs moisture or water from the air. It is incompatible with strong oxidising agents. On decomposition, rhodium trichloride emits hydrogen chloride, carbon monoxide, carbon dioxide, and rhodium/rhodium oxides.

Chemical Properties

Rhodium trichloride is a red-brown or black, odorless solid or liquid

Potential Exposure

Rhodium trichloride is used in hydro- silylation, hydrogenation, carbonylation, oxidation, aryla- tion. See also “Rhodium Metal.” In plating operations and in catalyst preparation, the metal will be used as the trichloride.

Shipping

UN3260 Corrosive solid, acidic, inorganic, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, Technical Name Required.

Incompatibilities

Sensitive to humidity. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materi- als, strong bases, strong acids, oxoacids, and epoxides.

Waste Disposal

Recovery and reclaiming wherever possible in view of high economic value. See “Rhodium Metal.”

Rhodium (III) chloride trihydrate(13569-65-8)Related Product Information

• Sodium chloride
• Chromium(III) chloride
• Choline chloride
• Antimony trichloride
• Calcium chloride
• Ruthenium(III) chloride hydrate
• Ammonium chloride
• Rhodium
• Titanous chloride
• Iridium(III) chloride hydrate
• Tributyltin chloride
• Calcium chloride hexahydrate
• Benzyltriethylammonium chloride
• Boron trichloride
• Rhodium(III) Chloride
• NEODYMIUM CHLORIDE
• Nickel(II) chloride hexahydrate
• Iron chloride hexahydrate
• Rhodium Chloride Trihydrate