TIGLOYL CHLORIDE Chemical Properties

Boiling point:

145 °C

Density 

1,08 g/cm³

refractive index 

n20/D 1.471

Flash point:

22 °C

storage temp. 

-20°C

solubility 

soluble in Chloroform, Methanol

form 

clear liquid

color 

Colorless to Almost colorless

InChI

1S/C5H7ClO/c1-3-4(2)5(6)7/h3H,1-2H3/b4-3+

InChIKey

TUNLYEHIVPWOHK-ONEGZZNKSA-N

SMILES

C\C=C(/C)C(Cl)=O

Safety Information

Hazard Codes 

T

Risk Statements 

10-23/24/25-34

Safety Statements 

16-26-36/37/39-45

RIDADR 

3265

WGK Germany 

3

HazardClass 

8/3

PackingGroup 

II

HS Code 

2916199590

Storage Class

3 - Flammable liquids

Hazard Classifications

Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B

TIGLOYL CHLORIDE Usage And Synthesis

Chemical Properties

Clear Colourless Oil

Uses

Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.

Synthesis Reference(s)

Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5

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