ChemicalBook > CAS DataBase List > TIGLOYL CHLORIDE

TIGLOYL CHLORIDE

Product Name
TIGLOYL CHLORIDE
CAS No.
35660-94-7
Chemical Name
TIGLOYL CHLORIDE
Synonyms
Tiglyl chloride;TIGLOYL CHLORIDE;Tiglic acid chloride;2-Methylcrotonic acid chloride;(E)-2-methylcrotonoyl chloride;(E)-2-Methyl-2-butenoyl chloride;(E)-2-METHYL-BUT-2-ENOYL CHLORIDE;(2E)-2-Methylbut-2-enoyl chloride;TRANS-2-METHYL-2-BUTENOYL CHLORIDE;(E)-2,3-Dimethylacryloyl chloride
CBNumber
CB7769801
Molecular Formula
C5H7ClO
Formula Weight
118.56
MOL File
35660-94-7.mol
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TIGLOYL CHLORIDE Property

Boiling point:
145 °C
Density 
1,08 g/cm3
refractive index 
n20/D 1.471
Flash point:
22 °C
storage temp. 
-20°C
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Safety

Hazard Codes 
T
Risk Statements 
10-23/24/25-34
Safety Statements 
16-26-36/37/39-45
RIDADR 
3265
WGK Germany 
3
HazardClass 
8/3
PackingGroup 
II
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H226Flammable liquid and vapour

H290May be corrosive to metals

H301Toxic if swalloed

H311Toxic in contact with skin

H314Causes severe skin burns and eye damage

H331Toxic if inhaled

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P234Keep only in original container.

P240Ground/bond container and receiving equipment.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P310Immediately call a POISON CENTER or doctor/physician.

P390Absorb spillage to prevent material damage.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P405Store locked up.

P406Store in corrosive resistant/… container with a resistant inner liner.

P403+P235Store in a well-ventilated place. Keep cool.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
688606
Product name
trans-2-Methyl-2-butenoyl chloride
Purity
≥97.0%
Packaging
1g
Price
$138
Updated
2021/12/16
Sigma-Aldrich
Product number
688606
Product name
trans-2-Methyl-2-butenoyl chloride
Purity
≥97.0%
Packaging
5g
Price
$385
Updated
2021/12/16
TCI Chemical
Product number
T1811
Product name
Tigloyl Chloride
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$233
Updated
2021/12/16
TRC
Product number
T440130
Product name
TigloylChloride
Packaging
10g
Price
$325
Updated
2021/12/16
SynQuest Laboratories
Product number
2316-5-E0
Product name
Tigloyl chloride
Packaging
5 g
Price
$328
Updated
2021/12/16
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TIGLOYL CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Clear Colourless Oil

Uses

Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.

Synthesis Reference(s)

Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5

TIGLOYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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TIGLOYL CHLORIDE Suppliers

J & K SCIENTIFIC LTD.
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010-82848833- ;010-82848833-
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86-10-82849933
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jkinfo@jkchemical.com;market6@jkchemical.com
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China
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TCI (Shanghai) Development Co., Ltd.
Tel
021-67121386 / 800-988-0390
Fax
021-67121385
Email
Sales-CN@TCIchemicals.com
Country
China
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Energy Chemical
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021-58432009-
Fax
021-58436166
Email
sales8178@energy-chemical.com
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China
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Shanghai Hanhong Scientific Co.,Ltd.
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;021-54306202- ;
Fax
13764082696
Email
jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com;jerry.ma@hanhonggroup.com
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China
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Chemsky(shanghai)International Co.,Ltd.
Tel
021-50135380
Email
shchemsky@sina.com
Country
China
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32358
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Hangzhou Sage Chemical Co., Ltd.
Tel
0571-86818502
Fax
Pls mail us for more information!
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info@sagechem.com
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China
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TOKYO CHEMICAL INDUSTRY CO., LTD.
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03-3668-0489
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03-3668-0520
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Sales-JP@TCIchemicals.com
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Japan
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9ding chemical ( Shanghai) Limited
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4009209199
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86-021-52271987
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sales@9dingchem.com
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China
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Letopharm Limited
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+86-21-5821 5861
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+86-21-5106 2861
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sales@letopharm.com
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Shanghai Leto Pharmatech Co.,Ltd.
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Fax
QQ: 1375988926
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490873513@qq.com
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China
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35660-94-7, TIGLOYL CHLORIDERelated Search:


  • TRANS-2-METHYL-2-BUTENOYL CHLORIDE
  • TIGLOYL CHLORIDE
  • (E)-2-methylcrotonoyl chloride
  • Tiglyl chloride
  • (E)-2-METHYL-BUT-2-ENOYL CHLORIDE
  • (E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride
  • (E)-2-Methyl-2-butenoic acid chloride
  • 2-Methylcrotonic acid chloride
  • Tiglic acid chloride
  • (E)-2,3-Dimethylacryloyl chloride
  • 3-cis-Methyl-methacryloyl chloride
  • 2-Butenoyl chloride, 2-Methyl-, (2E)-
  • (E)-2-Methyl-2-butenoyl chloride
  • (2E)-2-Methylbut-2-enoyl chloride
  • trans-2-Methyl-2-butenoyl chloride >=97.0%
  • (E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chlo
  • 35660-94-7