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TIGLOYL CHLORIDE

Product Name
TIGLOYL CHLORIDE
CAS No.
35660-94-7
Chemical Name
TIGLOYL CHLORIDE
Synonyms
Tiglyl chloride;TIGLOYL CHLORIDE;Tiglic acid chloride;2-Methylcrotonic acid chloride;(E)-2-methylcrotonoyl chloride;(E)-2-Methyl-2-butenoyl chloride;(E)-2-METHYL-BUT-2-ENOYL CHLORIDE;(2E)-2-Methylbut-2-enoyl chloride;TRANS-2-METHYL-2-BUTENOYL CHLORIDE;(E)-2,3-Dimethylacryloyl chloride
CBNumber
CB7769801
Molecular Formula
C5H7ClO
Formula Weight
118.56
MOL File
35660-94-7.mol
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TIGLOYL CHLORIDE Property

Boiling point:
145 °C
Density 
1,08 g/cm3
refractive index 
n20/D 1.471
Flash point:
22 °C
storage temp. 
-20°C
solubility 
soluble in Chloroform, Methanol
form 
clear liquid
color 
Colorless to Almost colorless
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Safety

Hazard Codes 
T
Risk Statements 
10-23/24/25-34
Safety Statements 
16-26-36/37/39-45
RIDADR 
3265
WGK Germany 
3
HazardClass 
8/3
PackingGroup 
II
HS Code 
2916199590
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
688606
Product name
trans-2-Methyl-2-butenoyl chloride
Purity
≥97.0%
Packaging
5g
Price
$517
Updated
2025/07/31
Sigma-Aldrich
Product number
688606
Product name
trans-2-Methyl-2-butenoyl chloride
Purity
≥97.0%
Packaging
1g
Price
$166
Updated
2023/06/20
TCI Chemical
Product number
T1811
Product name
Tigloyl Chloride
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$242
Updated
2025/07/31
TRC
Product number
T440130
Product name
Tigloyl Chloride
Packaging
10g
Price
$325
Updated
2021/12/16
SynQuest Laboratories
Product number
2316-5-E0
Product name
Tigloyl chloride
Packaging
5G
Price
$328
Updated
2021/12/16
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TIGLOYL CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Clear Colourless Oil

Uses

Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.

Synthesis Reference(s)

Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5

TIGLOYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

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35660-94-7, TIGLOYL CHLORIDERelated Search:

Methacryloyl chloride Tiglic acid 5,6-BENZOCOUMARIN-3-CARBONYL CHLORIDE (E)-2-METHYL-3-PHENYL-ACRYLOYL CHLORIDE 1-CYCLOHEXENECARBONYL CHLORIDE 1-(3-METHYL-BUTYL)-2-OXO-1,2-DIHYDRO-QUINOLINE-3-CARBONYL CHLORIDE 2H-CHROMENE-3-CARBONYL CHLORIDE 6-CHLORO-2H-1-BENZOPYRAN-3-CARBONYL CHLORIDE COUMARIN-3-CARBOXYLIC ACID CHLORIDE BUTTPARK 52\08-05 STILBENE DICARBOXYLIC ACID CHLORIDE TIGLOYL CHLORIDE

  • TRANS-2-METHYL-2-BUTENOYL CHLORIDE
  • TIGLOYL CHLORIDE
  • (E)-2-methylcrotonoyl chloride
  • Tiglyl chloride
  • (E)-2-METHYL-BUT-2-ENOYL CHLORIDE
  • (E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride
  • (E)-2-Methyl-2-butenoic acid chloride
  • 2-Methylcrotonic acid chloride
  • Tiglic acid chloride
  • (E)-2,3-Dimethylacryloyl chloride
  • 3-cis-Methyl-methacryloyl chloride
  • 2-Butenoyl chloride, 2-Methyl-, (2E)-
  • (E)-2-Methyl-2-butenoyl chloride
  • (2E)-2-Methylbut-2-enoyl chloride
  • trans-2-Methyl-2-butenoyl chloride >=97.0%
  • (E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chlo
  • <i>trans</i>-2-Methyl-2-butenoyl chloride
  • 35660-94-7