TIGLOYL CHLORIDE Property

Boiling point:

145 °C

Density 

1,08 g/cm³

refractive index 

n20/D 1.471

Flash point:

22 °C

storage temp. 

-20°C

solubility 

soluble in Chloroform, Methanol

form 

clear liquid

color 

Colorless to Almost colorless

Safety

Hazard Codes 

T

Risk Statements 

10-23/24/25-34

Safety Statements 

16-26-36/37/39-45

RIDADR 

3265

WGK Germany 

3

HazardClass 

8/3

PackingGroup 

II

HS Code 

2916199590

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

TIGLOYL CHLORIDE Chemical Properties,Usage,Production

Chemical Properties

Clear Colourless Oil

Uses

Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.

Synthesis Reference(s)

Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5