Phenyl-t-butylether Chemical Properties

Melting point:

-17--16℃

Boiling point:

184°C

Density 

0.924

refractive index 

1.488

Flash point:

184°C

storage temp. 

Sealed in dry,Room Temperature

Safety Information

HS Code 

2909309090

Phenyl-t-butylether Usage And Synthesis

Synthesis

A 4-mL vial was charged with bromobenzene (63 mg, 0.40 mmol), Pd(dba)2 (11.5 mg, 0.0200 mmol), Ph5FcP-(t-Bu)2 (14.2 mg, 0.0200 mmol), and sodium tert-butoxide (47 mg, 0.48 mmol). Anhydrous toluene (2 mL) was added, and the vial was sealed with a cap containing a PTFE septum and removed from the dry box. The reaction mixture was stirred at room temperature for 23 h. The reaction solution was then adsorbed onto silica gel, and the product was isolated by eluting with EtOAc/hexanes (0 to 10% gradient) to give the ether (58 mg, 97%).
Reference: Kataoka, N.; Shelby, Q.; Stambuli, J. P.; Hartwig, J. F. J. Org. Chem. 2002, 67, 5553–5566.

Uses

tert-Butoxybenzene was studied in the analysis of the color and flavor improvement of different starter cultures on northern air-dried sausage.

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