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2-(Di-tert-butylphosphino)-1-phenylindole

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2-(Di-tert-butylphosphino)-1-phenylindole Basic information

Product Name:
2-(Di-tert-butylphosphino)-1-phenylindole
Synonyms:
  • 2-(Di-tert-butylphosphino)-1-phenylindole
  • 2-(Di-tert-butylphosphino)-1-phenylindole 96%
  • 98% [cataCXiuM PIntB]
  • cataCXium(R) PIntB
  • 2-(di-tert-butylphosphino)-1-phenyl-1H-indole
  • N-Phenyl-2-(di-tert-butylphosphino)indole
  • N-Phenylindol-2-yl-di-tert-butylphosphine
  • N-Phenyl-2-(di-t-butylphosphino)indol,98%
CAS:
740815-37-6
MF:
C22H28NP
MW:
337.44
Product Categories:
  • Achiral Phosphine
  • Aryl Phosphine
Mol File:
740815-37-6.mol
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2-(Di-tert-butylphosphino)-1-phenylindole Chemical Properties

Melting point:
90-92℃ (methanol )
Boiling point:
455.4±27.0 °C(Predicted)
storage temp. 
Refrigerator, under inert atmosphere
solubility 
Acetonitrile (Slightly), Benzene (Slightly), Chloroform (Slightly)
form 
Powder
color 
white to yellow
Sensitive 
air sensitive
BRN 
9924511
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Safety Information

WGK Germany 
3
HS Code 
29339900
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2-(Di-tert-butylphosphino)-1-phenylindole Usage And Synthesis

Reaction

  1. Useful ligand for the Pd-catalyzed amination reaction.
  2. Ligand used for the Pd-catalyzed arylation of phenols.
  3. Useful ligand for the Suzuki-Miyaura coupling.
  4. Ligand used for the Sonagashira reaction of aryl bromides.

Chemical Properties

White to yellow powder

Uses

N-Phenyl-2-(di-tert-butylphosphino)indole is a catalyst for the selective monoarylation of ammonia with different aryl bromides and chlorides.

General Description

sold in collaboration with Solvias AG

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