Dimethyl chloromalonate Chemical Properties

Boiling point:

105-106 °C/19 mmHg (lit.)

Density 

1.305 g/mL at 25 °C (lit.)

refractive index 

n20/D 1.437(lit.)

Flash point:

224 °F

storage temp. 

Keep in dark place,Sealed in dry,Room Temperature

form 

clear liquid

pka

9.02±0.46(Predicted)

color 

Colorless to Light yellow

BRN 

1768415

CAS DataBase Reference

28868-76-0(CAS DataBase Reference)

Safety Information

Hazard Codes 

C

Risk Statements 

34

Safety Statements 

26-36/37/39-45

RIDADR 

UN 3265 8/PG 2

WGK Germany 

3

F 

21

HazardClass 

8

PackingGroup 

III

HS Code 

2917198090

MSDS

• Language:English Provider:SigmaAldrich

Dimethyl chloromalonate Usage And Synthesis

Uses

Dimethyl chloromalonate is suitable for use in the synthesis of 4,5,6-trichloropyrimidine. It may be used in the stereoselective synthesis of highly functionalized nitrocyclopropanes. It may be used in one-pot synthesis of tetra-alkoxycarbonylallylidenetriphenylphosphoranes.

General Description

Dimethyl chloromalonate (dimethyl 2-chloromalonate) is a dialkyl 2-substituted malonate. Carbanions of dimethyl chloromalonate are reported to react with naphthoquinone derivatives, via vicarious nucleophilic substitution or oxidative nucleophilic substitution of hydrogen processes. Dimethyl chloromalonate is reported to react with hydroquinone and monosubstituted hydroquinones to afford 2-oxido-benzo[b]furan derivatives. Synthesis of dimethyl 2-chloromalonate, via chlorination of dimethyl malonate has been reported.

Dimethyl chloromalonate(28868-76-0)Related Product Information

• N,N-Dimethylformamide
• Dimethyl fluoromalonate
• Malononitrile
• Dimethyl sulfide
• Dimethyl methylmalonate
• Dimethyl fumarate
• Diethyl malonate
• Dimethyl phthalate
• Dimethyl sulfoxide
• ETHANE
• Dimethyl malonate
• Dimethyl ether
• Malonic acid
• Dimethyl acetamidomalonate
• Diethyl methylmalonate
• Dimethyl isobutylmalonate
• DIMETHYL METHOXYMALONATE
• 2,2-DIMETHYL-MALONIC ACID DIMETHYL ESTER