(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Basic information
- Product Name:
- (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
- Synonyms:
-
- (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
- (S)-AMAC
- Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-
- (S,S)-AMAC
- (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
- CID 135483535
- CAS:
- 259259-80-8
- MF:
- C32H38CoN2O4
- MW:
- 573.59
- Product Categories:
-
- Asymmetric Synthesis
- Catalysts for Organic Synthesis
- Classes of Metal Compounds
- Co (Cobalt) Compounds
- Homogeneous Catalysts
- Metal Complexes
- Synthetic Organic Chemistry
- Transition Metal Compounds
- Mol File:
- 259259-80-8.mol
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(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties
- Melting point:
- 242-246°C
- storage temp.
- under inert gas (nitrogen or Argon) at 2-8°C
- form
- powder to crystal
- color
- Orange to Brown
- optical activity
- [α]/D 309°, c = 0.1 in chloroform
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(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Usage And Synthesis
Uses
Catalyst for:
- Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
- Enantioselective borohydride reduction
- Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
- Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones
(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)Supplier
J & K SCIENTIFIC LTD.
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- 010-82848833 400-666-7788
- jkinfo@jkchemical.com
Meryer (Shanghai) Chemical Technology Co., Ltd.
- Tel
- 021-61259108 18621169109
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TCI (Shanghai) Development Co., Ltd.
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- 021-67121386
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Energy Chemical
- Tel
- 021-021-58432009 400-005-6266
- sales8178@energy-chemical.com
Shanghai Longsheng chemical Co.,Ltd.
- Tel
- 021-58099652-8005 13585536065
- bin.wu@shlschem.com
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(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)(259259-80-8)Related Product Information
- N-Benzylcinchonidinium chloride
- (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
- (1S,2S)-1,2-BIS(2,4,6-TRIMETHYLPHENYL)ETHYLENEDIAMINE
- MESO-1,2-BIS(P-TOLYL)ETHYLENEDIAMINE
- (R)-(1-(2,4,6-Trimethylphenyl)ethyl)amine
- (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)