(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Chemical Properties

Melting point:

246-250°C

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

optical activity

[α]/D 291°, c = 0.1 in chloroform

Safety Information

Hazard Codes 

Xn

Risk Statements 

20/21/22-36/37/38

Safety Statements 

22-24/25-36/37/39

WGK Germany 

2

HS Code 

2942.00.3500

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) Usage And Synthesis

Uses

• Schiff base-cobalt complex catalyst for asymmetric borohydride reduction of carbonyl compounds

• Enantioselective borohydride reduction
• Stereoselective preparation of aryl alcohols via asymmetric reduction of aryl ketones with borohydride
• Stereoselective borohydride reduction of diketones to diols
• Stereoselective preparation of optically active deuterated primary alcohols via enantioselective borodeuteride reduction of aldehydes
• Stereoselective preparation of β-hydroxy esters via dynamic kinetic resolution of alkylketo esters with enantioselective borohydride reduction
• Chemoselective, diastereoselective, and enantioselective borohydride reduction of 1,3-diketones
• Asymmetric synthesis of diarylhydroxypropanones by stereoselective reduction of alkyldiaryldiketones

(1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)(361346-80-7)Related Product Information

• Cobalt
• (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
• (S)-1-PHENYL-2-(P-TOLYL)ETHYLAMINE
• 1,2-Diphenylethylenediamine
• Benzenemethanamine,a,2,4-trimethyl-, (aS)-
• Benzenemethanamine, α,2,4,6-tetramethyl-, (αS)-
• (1R,2R)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
• MESO-1,2-BIS(P-TOLYL)ETHYLENEDIAMINE
• (1R,2R)-1,2-BIS(2,4,6-TRIMETHYLPHENYL)ETHYLENEDIAMINE