(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one Chemical Properties

Boiling point:

158-160 °C(lit.)

Density 

1.025 g/mL at 25 °C(lit.)

refractive index 

n20/D 1.4820(lit.)

storage temp. 

under inert gas (nitrogen or Argon) at 2-8°C

Sensitive 

Air Sensitive

Safety Information

Hazard Codes 

Xn

Risk Statements 

22-37/38-41

Safety Statements 

26-39

RIDADR 

UN1224

WGK Germany 

3

F 

10-23

HazardClass 

3

PackingGroup 

III

HS Code 

29337900

MSDS

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(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one Usage And Synthesis

Uses

Bicyclo[3.2.0]hept-2-en-6-one is widely utilized to study enantioselective Baeyer-Villiger oxidation of (±)-cis-bicyclo(3.2.0)hept-2-en-6-one. It is used in the synthesis of a series of chalcone derivatives by reacting with arylaldehydes. It is also used to analyze the extremophile enzymes (monooxygenase and hydrolases) in microorganisms which are isolated from a deep-water petroleum reservoir and at high temperatures using fluorogenic assays and multibioreactions.

General Description

(±)-cis-bicyclo(3.2.0)hept-2-en-6-one undergoes preparative scale Baeyer–Villiger biooxidation at high concentration using recombinant Escherichia coli biocatalyst and adsorbent resin (in situ substrate feeding and product removal).

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