Basic information Safety Supplier Related

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine

Basic information Safety Supplier Related

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Basic information

Product Name:
(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine
Synonyms:
  • (R)-1-[(R)-1- (Dicyclohexylphosphino)ethyl]- 2-[2- (diphenylphosphino)phenyl]ferro cene
  • (1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene
  • (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine, Walphos SL-W003-1
  • Ferrocene,1-[(1R)-1-(dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]-, (1S)-
  • (R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine
  • (R)-(-)-1-[(R)-2-(2''-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine
CAS:
565184-29-4
MF:
C42H48FeP210*
MW:
670.623042
Mol File:
565184-29-4.mol
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(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Chemical Properties

Melting point:
87-96 °C
alpha 
-8° ±2° (c 0.5, CHCl3)
form 
Powder
color 
orange
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(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphine Usage And Synthesis

Uses

(1S)-1-[(1R)-1-(Dicyclohexylphosphino)ethyl]-2-[2-(diphenylphosphino)phenyl]ferrocene is used in preparation of chiral Piperidines via asymmetric Hydrogenation of Dehydropiperidines using metal chiral Phosphine catalyst complexes.

Reactions

1. Enantioselective synthesis of chiral fluoropiperidine via asymmetric hydrogenation of a vinyl fluoride.
2. Palladium/ClickFerrophos – Catalyzed asymmetric domino allylstannylation-Heck reaction of o-formylaryl triflate.
3. Catalytic asymmetric alkylation of acylsilanes.

(R)-(-)-1-[(R)-2-(2'-Diphenylphosphinophenyl)ferrocenyl]ethyldicyclohexylphosphineSupplier

Shanghai Pansopharm Technology Co., Ltd.
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021-20962833 15316628753
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Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.
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0371-65511006 18625597674
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LaaJoo
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021-60702684 18516024827
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Aikon International Limited
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Shanghai Anyinuo Biomedical Technology Co., Ltd.
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