Basic information Safety Supplier Related

ETHYL DIAZOACETOACETATE

Basic information Safety Supplier Related

ETHYL DIAZOACETOACETATE Basic information

Product Name:
ETHYL DIAZOACETOACETATE
Synonyms:
  • 2-Diazo-3-oxobutanoic acid ethyl ester
  • 2-Diazo-3-oxobutyric acid ethyl
  • 2-Diazo-3-oxobutyric acid ethyl ester
  • 2-Diazoacetoacetic acid ethyl ester
  • 3-Oxo-2-diazobutanoic acid ethyl ester
  • ETHYL DIAZOACETOACETATE
  • Butanoic acid, 2-diazo-3-oxo-, ethyl ester
  • Ethyl 2-diazoacetoacetate
CAS:
2009-97-4
MF:
C6H8N2O3
MW:
156.14
Product Categories:
  • Azo/Diazo Compounds
  • Nitrogen Compounds
  • Organic Building Blocks
Mol File:
2009-97-4.mol
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ETHYL DIAZOACETOACETATE Chemical Properties

Boiling point:
102-103 °C(Press: 12 Torr)
Density 
1.131 g/mL at 25 °C (lit.)
vapor pressure 
0.36 psi ( 20 °C)
refractive index 
n20/D 1.474(lit.)
Flash point:
185 °F
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
HS Code 
29270000
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ETHYL DIAZOACETOACETATE Usage And Synthesis

Synthesis Reference(s)

Tetrahedron Letters, 5, p. 2285, 1964 DOI: 10.1002/lipi.19640660210

General Description

Ethyl diazoacetoacetate is a diazo compound. It participates in Rh2(OAc)4-catalyzed reactions with arylalkylamines and diarylamines. Reaction of ethyl diazoacetoacetate with N-methyl pyrrole and pyrrole derivatives has been studied.

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