(+)-ISOPINOCAMPHEOL Chemical Properties

Melting point:

52-55 °C

Boiling point:

219 °C(lit.)

Density 

0.8389 (rough estimate)

refractive index 

1.4710 (estimate)

Flash point:

93 °C

pka

15.35±0.60(Predicted)

form 

solid

optical activity

[α]20/D +35.1°, c =20 in ethanol

InChI

1S/C10H18O/c1-6-8-4-7(5-9(6)11)10(8,2)3/h6-9,11H,4-5H2,1-3H3/t6-,7+,8-,9-/m0/s1

InChIKey

REPVLJRCJUVQFA-KZVJFYERSA-N

SMILES

C[C@@H]1[C@@H](O)CC2CC1C2(C)C

LogP

2.805 (est)

Safety Information

WGK Germany 

3

Storage Class

11 - Combustible Solids

MSDS

• Language:English Provider:SigmaAldrich

(+)-ISOPINOCAMPHEOL Usage And Synthesis

Uses

(1S,2S,3S,5R)-(+)-Isopinocampheol may be used in the preparation of

• thermotropic chiral nematic side-chain copolymers
• ortho-(diphenylphosphino)phenylphosphonous acid di[(1S,2S,3S,5R)-2,6,6-trimethyl-bicyclo[3.1.1]-hept-3-yl]ester, a phosphino-phosphonite ligand
• O,O′bis[(1S,2S,3S,5R)2,6,6-trimethylbicyclo[3.1.1]hept-3-yl] dithiophosphoric acid, a bioactive compound with antifungal effect

General Description

(1S,2S,3S,5R)-(+)-Isopinocampheol is a chiral terpenol.

Purification Methods

Dissolve it in Et2O, dry over MgSO4, filter, evaporate, then recrystallise it from pet ether. Also recrystallise it from aqueous EtOH and distil it in a vacuum. [Kergomard & Geneix Bull Soc Chim Fr 394 1958, Zweifel & Brown J Am Chem Soc 86 393 1964.] The 3,4-dinitrobenzoyl derivative has m 100-101o, the phenylcarbamoyl derivative has m 137-138o and the acid -phthalate has m 125-126o. [Beilstein 6 III 282, 283.]

(+)-ISOPINOCAMPHEOL(27779-29-9)Related Product Information

• ISOPINOCAMPHEOL, DL-,DL-ISOPINOCAMPHEOL
• (+)-ISOPINOCAMPHEOL,(1S,2S,3S,5R)-(+)-ISOPINOCAMPHEOL,ISOPINOCAMPHEOL, (+)-,(1S,2S,5R)-(+)-Isopinocampheol
• ISOPINOCAMPHEOL, DL-(RG)
• (-)-Isopinocampheol
• ISOPINOCAMPHEOL, (-)-,(-)-ISOPINOCAMPHEOL,(-)-ISOPINOCAMPHEOL WITH GC