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2-Furanacrolein

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2-Furanacrolein Basic information

Product Name:
2-Furanacrolein
Synonyms:
  • B-(2-FURFURYLIDENE)ACETALDEHYDE
  • B-(2-FURYL)ACROLEIN
  • BETA-(2-FURYLACROLEIN) TRANS-ISOMER
  • (E)-3-FURAN-2-YL-PROPENAL
  • FURAN-2-ACROLEIN
  • FURYL ACROLEIN
  • FEMA 2494
  • AKOS BBS-00003241
CAS:
623-30-3
MF:
C7H6O2
MW:
122.12
EINECS:
210-785-3
Product Categories:
  • Alphabetical Listings
  • E-F
  • Heterocycles
  • Furan&Benzofuran
  • aldehyde Flavor
  • Flavors and Fragrances
Mol File:
623-30-3.mol
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2-Furanacrolein Chemical Properties

Melting point:
49-55 °C(lit.)
Boiling point:
143 °C37 mm Hg(lit.)
Density 
1.1483 (rough estimate)
refractive index 
1.5286 (estimate)
FEMA 
2494 | 3-(2-FURYL)ACROLEIN
Flash point:
211 °F
storage temp. 
2-8°C
form 
powder to crystal
color 
White to Light yellow to Dark green
Odor
at 1.00 % in dipropylene glycol. green grassy fruity spicy vanilla nutty woody cinnamon
Odor Type
spicy
Water Solubility 
insoluble
Sensitive 
Air Sensitive
JECFA Number
1497
BRN 
107570
LogP
1.74
CAS DataBase Reference
623-30-3(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenal, 3-(2-furanyl)-(623-30-3)
EPA Substance Registry System
2-Propenal, 3-(2-furanyl)- (623-30-3)
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Safety Information

Hazard Codes 
C
Risk Statements 
34
Safety Statements 
26-27-28-36/37/39-45-24/25
RIDADR 
UN 1759 8/PG 2
WGK Germany 
3
RTECS 
LT8528500
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29321900

MSDS

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2-Furanacrolein Usage And Synthesis

Chemical Properties

Colorless to light yellow liqui

Chemical Properties

3(2-Furyl)acrolein has a cooked spicy-herb odor and taste.

Occurrence

Reported found in ground and roasted coffee and rum

Definition

ChEBI: 3-(2-Furanyl)-2-propenal is a heteroarene.

Synthesis Reference(s)

The Journal of Organic Chemistry, 58, p. 2517, 1993 DOI: 10.1021/jo00061a027

General Description

Light brown powder. Cinnamon odor.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

2-Furanacrolein is an aldehyde. May become involved in exothermic self-condensation or polymerization reactions that are often catalyzed by acid. May generate flammable and/or toxic gases with azo, diazo compounds, dithiocarbamates, nitrides, and strong reducing agents. Can react with air to give first peroxo acids, and ultimately carboxylic acids. These autoxidation reactions are activated by light, catalyzed by salts of transition metals, and are autocatalytic (catalyzed by the products of the reaction). The addition of stabilizers (antioxidants) to shipments of aldehydes retards autoxidation.

Fire Hazard

Flash point data are not available for 2-Furanacrolein, but 2-Furanacrolein is probably combustible.

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