2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Basic information
- Product Name:
- 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- Synonyms:
-
- 2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
- Tris(trimethylsilyl)silanol
- Tris(trimethylsilyl)silanol >=95%
- Hydroxy-tris(trimethylsilyl)silane
- CAS:
- 7428-60-6
- MF:
- C9H28OSi4
- MW:
- 264.66
- Mol File:
- 7428-60-6.mol
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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Chemical Properties
- Boiling point:
- 235.1±23.0 °C(Predicted)
- Density
- 0.833±0.06 g/cm3(Predicted)
- pka
- 15.57±0.53(Predicted)
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2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)- Usage And Synthesis
Uses
Under a dual catalytic copper/photoredox manifold, this supersilanol has been demonstrated by the MacMillan lab to be an excellent reagent for the trifluoromethylation of alkyl halides and aryl halides to yield alkyl-CF3 and aryl-CF3 in high yields. In both cases, these reactions exhibit wide substrate scope with good functional group tolerance. More specifically, a variety of 5-membered and 6-membered heteroaryl halides can be readily converted to the corresponding trifluoromethylheteroarenes under mild conditions. To be use in conjunction with dMesSCF3 (901466) and Ir photocatalyst (902217 or 902225).
2-Trisilanol, 1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-Supplier
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