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1-Naphthylboronic acid

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1-Naphthylboronic acid Basic information

Product Name:
1-Naphthylboronic acid
Synonyms:
  • 1-Naphthaleneboronic Acid (contains varying amounts of Anhydride)
  • 1-Naphthylboronic acid, min. 97%
  • (1-Naphthyl)boranediol
  • (1-Naphthyl)boranic acid
  • (1-Naphthyl)dihydroxyborane
  • 1-(Dihydroxyboryl)naphthalene
  • 1-Naphthylboranic acid
  • 1-Naphthaleneboronic acid,97%
CAS:
13922-41-3
MF:
C10H9BO2
MW:
171.99
EINECS:
604-119-4
Product Categories:
  • Heterocyclic Compounds
  • organic or inorganic borate
  • Boronic Acid
  • Naphthalene
  • Organoborons
  • B (Classes of Boron Compounds)
  • Aryl Boronic Acids
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Organometallic Reagents
  • Unsubstituted Aryl Boronic Acids
  • OLED materials,pharm chemical,electronic
  • Boronate Ester
  • Potassium Trifluoroborate
  • blocks
  • BoronicAcids
  • Boronic Acid series
  • Naphthalene derivatives
  • Boronic acids
Mol File:
13922-41-3.mol
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1-Naphthylboronic acid Chemical Properties

Melting point:
208-214 °C(lit.)
Boiling point:
381.9±25.0 °C(Predicted)
Density 
1.21±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in DMSO, Methanol
form 
Powder
pka
8.53±0.30(Predicted)
color 
Off-white to pink beige
Water Solubility 
2.5 g/100 mL
BRN 
2937504
InChI
InChI=1S/C10H9BO2/c12-11(13)10-6-5-8-3-1-2-4-9(8)7-10/h1-7,12-13H
InChIKey
HUMMCEUVDBVXTQ-UHFFFAOYSA-N
SMILES
C1=C2C(C=CC=C2)=CC=C1B(O)O
CAS DataBase Reference
13922-41-3(CAS DataBase Reference)
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Safety Information

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29319090

MSDS

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1-Naphthylboronic acid Usage And Synthesis

Chemical Properties

Off-white to pink beige powder. soluble in methanol. Insoluble in water.

Uses

1-Naphthaleneboronic acid is a useful synthetic intermediate. It is a reagent used to synthesize potassium aryltrifluoroborates which is a convenient precursor of arylboron difluoride lewis acids. It is also useful in the synthesis of polyaromatic hydrocarbons utilizing the Suzuki reaction.

Uses

Naphthalene-1-boronic acid can be used:
Methyl 5-bromo-2-(naphthalene-1-yl)benzoate, which is a starting material for the preparation of 9-anthracene-spirobenzofluorene host materials.
A bifunctional polymer used for the hydrolysis of cellulose.
9-(Naphthalene-1-yl)anthracene, which is a key intermediate for the preparation of anthracene derived molecular glass having blue emission.
1-Naphthaleneboronic acid can also be as a substrate in fluorometric boronic acid based saccharide sensors based on the Suzuki homocoupling reactions.

Precautions

Incompatible with oxidizing agents. Store in a cool, dry condition in a well sealed container. Store at room temperature.

1-Naphthylboronic acid Preparation Products And Raw materials

Raw materials

1-Naphthylboronic acidSupplier

Sunshine Optoelectronic Gold
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