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DIPHENYL SELENIDE

Basic information Safety Supplier Related

DIPHENYL SELENIDE Basic information

Product Name:
DIPHENYL SELENIDE
Synonyms:
  • DIPHENYL SELENIDE
  • DIPHENYLSELENIUM
  • SELENIUM DIPHENYL
  • PHENYL SELENIDE
  • (Phenylselanyl)benzene
  • 1,1’-selenobis-benzen
  • 1,1’-selenobisbenzene
  • Biphenyl selenide
CAS:
1132-39-4
MF:
C12H10Se
MW:
233.17
EINECS:
214-474-3
Product Categories:
  • Building Blocks
  • Organic Building Blocks
  • Selenium Compounds
  • organoselenides
Mol File:
1132-39-4.mol
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DIPHENYL SELENIDE Chemical Properties

Melting point:
3°C
Boiling point:
115-117 °C(lit.)
Density 
1.338 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.6465(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
liquid
color 
amber
Water Solubility 
Immiscible with water.
Sensitive 
Moisture Sensitive
Exposure limits
ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 1 mg/m3; TWA 0.2 mg/m3
CAS DataBase Reference
1132-39-4(CAS DataBase Reference)
EPA Substance Registry System
Diphenyl selenide (1132-39-4)
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Safety Information

Hazard Codes 
T,N
Risk Statements 
23/25-33-50/53
Safety Statements 
20/21-28-45-60-61
RIDADR 
UN 3082 9/PG 3
WGK Germany 
3
RTECS 
SX1825000
TSCA 
Yes
HazardClass 
6.1
PackingGroup 
II

MSDS

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DIPHENYL SELENIDE Usage And Synthesis

Chemical Properties

clear yellow to red-brown liquid

Uses

Diphenyl selenide is used for anti-selective Michael addition of thiols and their analogs to nitro-olefins.

General Description

Diphenyl selenide is an organoselenium compound. Its standard enthalpies of combustion, formation and the mean bond-dissociation energy have been calculated. Its potential as a neutral carrier to develop silver-selective membrane electrode has been investigated. Diphenyl selenide undergoes oxidation to form selenoxides on treating with N-bromosuccinimide followed by alkaline hydrolysis.

Safety Profile

Poison by ingestion. When heated to decomposition it emits toxic fumes of Se. See also SELENIUM COMPOUNDS

DIPHENYL SELENIDESupplier

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