BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Chemical Properties

Melting point:

55-60 °C (lit.)

Boiling point:

105°C/0.3mm

Flash point:

>230 °F

storage temp. 

room temp

solubility 

Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.

form 

Powder

color 

white

Sensitive 

air sensitive

BRN 

6253897

Major Application

environmental

InChI

1S/C18H5F10P/c19-7-9(21)13(25)17(14(26)10(7)22)29(6-4-2-1-3-5-6)18-15(27)11(23)8(20)12(24)16(18)28/h1-5H

InChIKey

OYNXPGGNQMSMTR-UHFFFAOYSA-N

SMILES

Fc1c(c(c(c(c1F)F)P(c3c(c(c(c(c3F)F)F)F)F)c2ccccc2)F)F

CAS DataBase Reference

5074-71-5(CAS DataBase Reference)

Safety Information

Hazard Codes 

Xi,Xn,T,F

Risk Statements 

36/37/38-20/21/22-40-63-43-23/24/25-45-67-66-36/38-11-36

Safety Statements 

26-36/37/39-22-36/37-24/25-23-53-16-9

RIDADR 

UN 1593 6.1/PG 3

WGK Germany 

3

Hazard Note 

Irritant

TSCA 

No

HS Code 

29310099

Storage Class

3 - Flammable liquids

Hazard Classifications

Eye Irrit. 2
Flam. Liq. 2
STOT SE 3

MSDS

• Language:English Provider:SigmaAldrich
• Language:English Provider:ACROS
• Language:English Provider:ALFA

BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)2.

General Description

Decafluorotriphenylphosphine (DFTPP) is commonly used as a check standard for the calibration of mass spectrum detector (MSD) prior to the analysis of samples under investigation.

BIS(PENTAFLUOROPHENYL)PHENYLPHOSPHINE(5074-71-5)Related Product Information

• (FORMYLMETHYLENE)TRIPHENYLPHOSPHORANE
• Pentafluorobenzene
• Phenyl phosphine
• Phosphine