ChemicalBook > Product Catalog > Chemical Reagents > Organic reagents > Phosphine ligand > (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Basic information
- Product Name:
- (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
- Synonyms:
-
- (S,S',R,R')-TANGPHOS
- (S,S,R,R)-TANGPHOS
- (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
- (1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE
- (1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS
- (1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS
- 2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-
- (2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane
- CAS:
- 470480-32-1
- MF:
- C16H32P2
- MW:
- 286.37
- Mol File:
- 470480-32-1.mol
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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Chemical Properties
- Melting point:
- 60-65 °C
- Boiling point:
- 353.6±12.0 °C(Predicted)
MSDS
- Language:English Provider:SigmaAldrich
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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE Usage And Synthesis
Uses
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Catalytic ligand used in:
- Preparation of α-borono-substituted alkylarenes by asymmetric hydroboration of styrenes catalyzed by copper(I)
- Enantioselective synthesis of spiroindane di-Me acetic acid via hydrogenation of spiroindane di-Me acetic acid catalyzed by Ru(II)
- Asymmetric γ-addition of thiols to allenoates
- Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
- Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANESupplier
J & K SCIENTIFIC LTD.
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Meryer (Shanghai) Chemical Technology Co., Ltd.
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Sigma-Aldrich
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Capot Chemical Co.,Ltd.
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Shandong Mingde Biotechnology Co., Ltd
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(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE(470480-32-1)Related Product Information
- (1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane (1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
- (1S,1'S,2R,2'R)-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE(1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
- (S,S)-1,2-BIS(TERT-BUTYLMETHYLPHOSPHINO)ETHANE
- 1,2-BIS(DIETHYLPHOSPHINO)ETHANE
- (1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE