(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Chemical Properties

Melting point:

220-230 °C

Boiling point:

588.1±38.0 °C(Predicted)

storage temp. 

2-8°C

pka

4.45±0.30(Predicted)

form 

Crystalline Powder

color 

White to off-white

BRN 

6664856

Safety Information

Hazard Codes 

Xi,Xn

Risk Statements 

36/37/38-22

Safety Statements 

37/39-26

WGK Germany 

3

HS Code 

29334990

MSDS

• Language:English Provider:ACROS

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE Usage And Synthesis

Chemical Properties

white to off-white crystalline powder

Uses

(S)-QUINAP can be used as a ligand:

• In the asymmetric hydrosilylation of alkyl and α, β-unsaturated ketones in the presence of Fe(OAc)₂.??????
• For the synthesis of chiral organoboron compounds by copper-catalyzed β-borylation of α,β-unsaturated esters.

[Ir(cod)Cl]₂ treated with ligand (S)-QUINAP forms an iridium complex. This complex is used as a catalyst for the enantioselective hydrogenation of olefins. (S)-QUINAP–Rh complex can be employed as a catalyst in enantioselective hydroboration/oxidation of perfluoroalkenes.

General Description

(S)-QUINAP is a bidentate ligand used in catalytic asymmetric hydroboration, hydrogenation, oxidation, and allylic alkylation reactions.

(R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE(149341-33-3)Related Product Information

• (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
• (R)-(+)-1-(2-DIPHENYLPHOSPHINO-1-NAPHTHYL)ISOQUINOLINE
• DIPHENYL(O-TOLYL)PHOSPHINE