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2-Vinyl-1,3-dioxolane

Basic information Safety Supplier Related

2-Vinyl-1,3-dioxolane Basic information

Product Name:
2-Vinyl-1,3-dioxolane
Synonyms:
  • 2-VINYL-1,3-DIOXOLAN
  • 2-VINYL-1,3-DIOXOLANE
  • ACROLEIN ETHYLENE ACETAL
  • VDL
  • RARECHEM AL BP 0670
  • 2-Ethenyl-1,3-dioxolane.
  • 2-VINYL-1,3-DIOXOLANE (VDL)
  • 1,3-Dioxolane, 2-ethenyl-
CAS:
3984-22-3
MF:
C5H8O2
MW:
100.12
EINECS:
223-626-8
Mol File:
3984-22-3.mol
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2-Vinyl-1,3-dioxolane Chemical Properties

Melting point:
117.3°C
Boiling point:
115-116 °C(lit.)
Density 
1.006 g/mL at 20 °C(lit.)
refractive index 
n20/D 1.431
Flash point:
58 °F
CAS DataBase Reference
3984-22-3(CAS DataBase Reference)
EPA Substance Registry System
1,3-Dioxolane, 2-ethenyl- (3984-22-3)
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Safety Information

Hazard Codes 
F,T+
Risk Statements 
11-25-27-36/37/38
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 1992 3/PG 1
WGK Germany 
2
RTECS 
JH7690000

MSDS

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2-Vinyl-1,3-dioxolane Usage And Synthesis

Synthesis

In a loop reactor with a total volume of 40 L, a Fixed catalyst bed with 2 L of a strongly acidic Ion exchanger (K 2431 from Bayer) was installed. On Reaction mixture with the approximate composition of 34 % acrolein, 36% ethylene glycol, 23% 2-vinyl-1,3-dioxolane, 4% water, and 3%  By-products are continuously at an internal temperature pumped in a circle at 5 ℃. The weight is continuously 4.6 kg Acrolein / h and 5.0 kg ethylene glycol / h, and the appropriate amount of reaction mixture (9.6 kg) is withdrawn. The outflowing reaction mixture is at the top of the extraction column and is fed with 1.0 kg of water / h. At the foot of the Extraction column, 7.3 l / h dean fed. The draining organic and aqueous phases become one subjected to fractional distillation, being from the organic phase first acrolein and then the product 2-Vinyl-1,3-dioxolane be distilled off.

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