BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE Chemical Properties

Melting point:

25-29 °C

Boiling point:

333.2±42.0 °C(Predicted)

form 

liquid

color 

colorless

Water Solubility 

Reacts with water.

Sensitive 

Moisture Sensitive

InChI

1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H

InChIKey

DFZQEHBNAJGDCT-UHFFFAOYSA-N

SMILES

FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F

Safety Information

Hazard Codes 

C

Risk Statements 

14-34

Safety Statements 

26-36/37/39-45

RIDADR 

UN3265

WGK Germany 

3

HazardClass 

8

PackingGroup 

II

Storage Class

4.3 - Hazardous materials which set free flammable gases upon contact with water

Hazard Classifications

Skin Corr. 1B
Water-react 3

BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE Usage And Synthesis

Uses

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE(142421-57-6)Related Product Information

• BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE, 98+%
• Bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine, min. 98%
• BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)CHLOROPHOSPHINE
• Chlorodiphenylphosphine
• BIS(3,5-DIMETHYLPHENYL)PHOSPHINE
• BIS(3,5-DI(TRIFLUOROMETHYL)PHENYL)PHOSPHINE
• METHYLPHENYLCHLOROPHOSPHINE
• BIS(3,5-DIMETHYLPHENYL)CHLOROPHOSPHINE