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ChemicalBook >  Product Catalog >  Organic Chemistry >  Hydrocarbons and derivatives >  (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine

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(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Basic information

Product Name:
(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
Synonyms:
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-Methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-aMine, Min. 98%
  • (11BR)-N,N-BIS[(R)-(-)-1-(2-METHOXYPHENYL)ETHYL]DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE,MIN.98%
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d
  • Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-, (11bR)-
  • (11bR)-N,N-bis[(1R)-1-(2-methoxyphenyl)ethyl]-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1'',2''-f][1,3,2]dioxaphosphepin-4-amine
  • (11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
CAS:
736158-72-8
MF:
C38H34NO4P
MW:
599.65
Product Categories:
  • Chiral Phosphine
  • CPN
Mol File:
736158-72-8.mol
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(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Chemical Properties

Boiling point:
760.0±70.0 °C(Predicted)
pka
-0.37±0.20(Predicted)
form 
Powder
color 
white
Sensitive 
moisture sensitive
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(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine Usage And Synthesis

Reaction

  1. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic and aliphatic substituted allylic halides to form branched chiral products from diverse Grignard and dialkyl zinc reagents.
  2. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from amines, stabilized carbanions, and aryl zinc reagents.
  3. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from alcohol.
  4. Ligand for the iridium catalyzed, highly regioselective, substitution reactions of a wide variety of aromatic and aliphatic substituted allylic carboxylates to form branched chiral products from thiolate.
  5. Ligand for the copper catalyzed, highly regioselective substitution reactions of a wide variety of aromatic and aliphatic substituted allylic halides to form branched chiral products from diverse organolithium compounds.

(11bR)-N,N-Bis[(R)-(-)-1-(2-methoxyphenyl)ethyl]dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amineSupplier

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