Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Basic information
- Product Name:
- Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
- Synonyms:
-
- )phenyl]-
- titanium,bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1h-pyrrol-1-yl
- BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE
- bis(cyclopentadienyl)bis(2,6-difluoro-3-(1H-pyrro
- photo sensitizer 784
- Bis(2,6-difluoro-3-(1-hydropyrrol-1-yl)phenyl)titanocene 99%
- Irgacure 784
- LS 784
- CAS:
- 125051-32-3
- MF:
- C30H12F4N2Ti
- MW:
- 524.3
- EINECS:
- 412-000-1
- Product Categories:
-
- argon ion laser scanning, holographic laser imaging, polyimide light curing, solidifying, PCB ink, PCB solder resist and light curing dental materials
- OLED
- Mol File:
- 125051-32-3.mol
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Chemical Properties
- Melting point:
- 160-170°C
- Density
- 1.43 at 20℃
- vapor pressure
- 0-0.001Pa at 25-50℃
- storage temp.
- below 5° C
- form
- Powder
- Hydrolytic Sensitivity
- 4: no reaction with water under neutral conditions
- InChI
- InChI=1S/2C10H6F2N.2C5.Ti/c2*11-8-3-4-10(9(12)7-8)13-5-1-2-6-13;2*1-2-4-5-3-1;/h2*1-6H;;;/q4*-1;+4
- InChIKey
- HRVFAWAOUBYIBB-UHFFFAOYSA-N
- SMILES
- FC1=C(N2C=CC=C2)C=CC(F)=[C-]1[Ti+4]12345678([C-]9=C(C=CC(N%10C=CC=C%10)=C9F)F)(C9=C1[C-]2C3=C49)C1=C5C6=C7[C-]81
- LogP
- 9.5 at 20℃
- Surface tension
- 72.4mN/m at 10g/L and 20℃
- EPA Substance Registry System
- Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- (125051-32-3)
Safety Information
- Hazard Codes
- F,Xn,N
- Risk Statements
- 36/37/38-51/53-62-48/22-11
- Safety Statements
- 26-36/37/39-61-36/37-33-22-7
- TSCA
- Yes
- HS Code
- 2914199090
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Usage And Synthesis
Description
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene, also known as Photosensitizer Irgacure 784 or HRcure-784, is an excellent photoinitiator used in a variety of holography material systems. It belongs to titanium‐complex free radical photoinitiator. As a highly active orange solid photoinitiator, Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene has good photoactivity, thermal stability, and low toxicity. Irgacure 784 has high solubility doped in liquid methyl methacrylate (MMA) monomer, far more than the photoinitiator PQ[1-2].
Uses
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE is a highly active orange solid photoinitiator with good photoactivity, thermal stability and low toxicity. As an active diluent, it is mainly used for UV and visible light curing of unsaturated prepolymers together with single or multi-functional vinyl monomers and oligomers.
Hazard
Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]; Flammable solid [Danger Flammable solids]; Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]
Properties and Applications
Photoinitiator 784 (also known as HRcure-784) is a highly active orange solid photoinitiator with good photo activity, thermal stability, and low toxicity. As an active diluent, it is mainly used with mono or multifunctional vinyl monomers and oligomers for UV and visible light curing unsaturated prepolymers. It is especially suitable for curing photosensitive resins for imaging or information storage in high-tech and high-value-added fields, information storage equipment, such as photosensitive layers, holography, laser direct imaging, stereolithography, etc. It can initiate the polymerization of unsaturated resins under the action of visible light or ultraviolet light. It can also be used for UV coatings, UV inks, and UV adhesives.
References
[1] Liu Y, et al. Volume holographic recording in Irgacure 784-doped PMMA photopolymer. Optics Express, 2017; 25: 20654-20662.
[2] Li Z, et al. Near‐Infrared‐Induced Cationic Polymerization Initiated by Using Upconverting Nanoparticles and Titanocene. Macromolecular Rapid Communications, 2019; 40: 1900047.
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanoceneSupplier
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