Product Identification

Product Name

2-Bromo-3-nitrotoluene

Synonyms

1-Bromo-2-methyl-6-nitrobenzene
2-Bromo-1-methyl-3-nitrobenzene
2-Bromo-3-methylnitrobenzene

CAS

41085-43-2

Formula

C7H6BrNO2

Molecular Weight

216.03

Beilstein Reference

4-05-00-00860

Physical and Chemical Properties

Solubility in water

-/26 g/L (25 C)

Melting Point

41.5

Boiling Point

282

Vapor Pressure

0.0058 (25 C)

Density

0.803 g/cm3 (25 C)

Partition Coefficient

2.98

Heat Of Vaporization

50.03 kJ/mol

First Aid Measures

Ingestion

If swallowed, wash out mouth with water provided person is conscious. Call a physician.

Inhalation

If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

Skin

In case of contact, immediately wash skin with soap and copious amounts of water. Remove contaminated clothing and shoes. Call a physician.

Eyes

In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers. Call a physician.

Handling and Storage

Storage

Keep tightly closed. Store in a cool dry place.

Hazards Identification

Inhalation

Material is irritating to mucous membranes and upper respiratory tract.

Hazards

Harmful solid or liquid (physical state is temperature dependent). Irritant. Emits toxic fumes under fire conditions.

EC Risk Phrase

20/21/22 36/37/38

EC Safety Phrase

26 36

Exposure Controls/Personal Protection

Personal Protection

Compatible chemical-resistant gloves. Chemical safety goggles. Protective clothing.

Respirators

Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU). Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator.

Exposure Effects

Causes eye and skin irritation. Harmful if swallowed, inhaled, or absorbed through skin.

Fire Fighting Measures

Flash Point

104

Fire Fighting

Extinguish with water spray, carbon dioxide, dry chemical powder or appropriate foam. Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.

Accidental Release Measures

Small spills/leaks

weep up, place in a bag and hold for waste disposal. Avoid raising dust. Ventilate area and wash spill site after material pickup is complete.

Stability and Reactivity

Incompatibilities

Strong oxidizing agents, Strong bases.

Decomposition

Carbon monoxide, Carbon dioxide, Nitrogen oxides, Hydrogen bromide gas.