Product Identification

Product Name

Isovaleraldehyde

Synonyms

3-Methylbutanal
3-Methylbutyraldehyde
Isoamyl aldehyde
Isopentaldehyde
Isovaleral
Isovaleric aldehyde

CAS

590-86-3

Formula

C5H10O

Molecular Weight

86.13

EINECS

209-691-5

RTECS

ES3450000

RTECS Class

Primary Irritant

Merck

13,5250

Beilstein/Gmelin

773692

Beilstein Reference

4-01-00-03291

EC Class

highly flammable, irritant

Physical and Chemical Properties

Appearance

Clear, colorless liquid with a pungent, apple-like odor.

Solubility in water

15 g/L (20 C)

Melting Point

-60

Boiling Point

90

Vapor Pressure

50 (25 C)

Density

0.8209 g/cm3 (0 C)

Partition Coefficient

1.25

Heat Of Vaporization

33.3 kJ/mol

Heat Of Combustion

-3107 kJ/mol

Usage

Flavor ingredient, fragrance ingredient in perfumes, chemical intermediate for isovaleric acid.

Vapor Density

2.96

Refractive Index

1.39 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Handling

Wash thoroughly after handling. Use only in a well ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid contact with heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.

Hazards Identification

Inhalation

May cause respiratory tract irritation. Vapors may cause dizziness or suffocation.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 11 36/37/38

EC Safety Phrase

S 16 29 33

UN (DOT)

2058

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

The toxological properties of this substance have not been fully investigated.

Poison Class

4

Fire Fighting Measures

Flash Point

-5

Autoignition

210

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Use water spray to keep fire-exposed containers cool Extinguishing media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.

Upper exp. limit

6.8

Lower exp. limit

1.7

Fire Potential

Flammable liquid and vapor.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Stability and Reactivity

Disposal Code

7

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, reducing agents, strong bases.

Decomposition

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2058

Hazard Class

3

Packing Group

II

HS Code

2912 19 00