Product Identification

Product Name

Aluminum 2,4-pentanedionate

Synonyms

Aluminum Chelate A
Dotite Al
Nacem Aluminum
Triacetylacetonate aluminum
Tris(2,4-pentanedione)aluminum
Tris(acetylacetonato)aluminum

CAS

13963-57-0

Formula

3C5H7AlO2

Molecular Weight

324.31

EINECS

237-741-6

RTECS

BD2230000

RTECS Class

Organometallic

Beilstein/Gmelin

4157942

Beilstein Reference

4-01-00-03662

EC Class

toxic, irritant

Physical and Chemical Properties

Appearance

Solid. Faint odor.

Solubility in water

3 g/L (20 C)

Melting Point

192 - 195

Boiling Point

315

Vapor Pressure

18 (214 C)

Density

1.204 g/cm3 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Wash mouth out with water.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Wash thoroughly after handling. Avoid contact with skin and eyes. Avoid ingestion and inhalation. Use only in a chemical fume hood.

Hazards Identification

Ingestion

Harmful if swallowed. May cause neurological effects.

Inhalation

Causes respiratory tract irritation. May cause neurological effects.

Skin

Causes skin irritation. May cause dermatitis.

Eyes

Causes eye irritation.

EC Risk Phrase

R 25 36

EC Safety Phrase

S 26 36/37/39 45

UN (DOT)

3282

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Autoignition

500

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container.

Stability and Reactivity

Disposal Code

9

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, strong bases.

Decomposition

Carbon monoxide, carbon dioxide, 2,4-pentanedione, aluminum oxide.

Transport Information

UN Number

3282

HS Code

2942 00 00