Product Identification

Product Name

2,2,6-Trimethyl-4H-1,3-dioxin-4-one

Synonyms

Diketene acetone adduct

CAS

5394-63-8

Formula

C7H10O3

Molecular Weight

142.16

EINECS

226-403-3

Beilstein/Gmelin

2408

Beilstein Reference

4-19-00-01604

EC Class

irritant

Physical and Chemical Properties

Solubility in water

Slightly soluble

Melting Point

12 - 13

Boiling Point

220

Vapor Pressure

0.12 (25 C)

Density

1.0879 g/cm3 (20 C)

Partition Coefficient

.15

Heat Of Vaporization

45.6 kJ/mol

Refractive Index

1.46 (20 C)

First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with running water for at least 20 minutes

Eyes

Flush with running water for at least 20 minutes.

Hazards Identification

Inhalation

Vapors may cause dizziness or suffocation. May cause irritation or burns.

Skin

May cause irritation or burns.

Eyes

See Skin.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 10 36

EC Safety Phrase

S 16 26 36

UN (DOT)

1993

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting Measures

Flash Point

82

Fire Fighting

Use of water spray when fighting fire may be inefficient. Small Fires: Dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam. Use water spray or fog; do not use straight streams.

Fire Potential

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

Stability and Reactivity

Disposal Code

1

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1993

HS Code

2932 99 95