Product Identification

Product Name

3-Bromopropionyl chloride

Synonyms

3-Bromopropionyl chloride
b-Bromopropanoyl chloride
b-Bromopropionyl chloride

CAS

15486-96-1

Formula

C3H4BrClO

Molecular Weight

171.42

EINECS

239-515-2

Beilstein/Gmelin

605453

Beilstein Reference

4-02-00-00765

Physical and Chemical Properties

Appearance

Clear yellow liquid.

Solubility in water

Slightly soluble

Boiling Point

55

Density

1.7 g/cm3

Refractive Index

1.49 (20 C)

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Keep away from sources of ignition. Store in a cool, dry place. Store in a tightly closed container. Corrosives area.

Handling

Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.

Hazards Identification

Ingestion

Causes gastrointestinal tract burns. The toxicological properties of this substance have not been fully investigated.

Inhalation

Causes chemical burns to the respiratory tract. The toxicological properties of this substance have not been fully investigated. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis and pulmonary edema.

Skin

Causes skin burns.

Eyes

Causes eye burns. Lachrymator. Lachrymator.

Hazards

Contact with metals may evolve flammable hydrogen gas.

EC Risk Phrase

R 34

EC Safety Phrase

S 26 36/37/39 45

UN (DOT)

1760

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

79

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. Extinguishing media: Do NOT use water directly on fire. Use foam, dry chemical, or carbon dioxide.

Fire Potential

Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Stability and Reactivity

Incompatibilities

Alcohols, oxidizing agents, strong bases.

Stability

No data.

Decomposition

Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide, hydrogen bromide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1760

Hazard Class

8

Packing Group

I; II; III