Product Identification

Product Name

MMTS

Synonyms

Methane, (methylsulfinyl)(methylthio)-
Methyl methylthiomethyl sulfoxide
Methylsulfinylmethylsulfanylmethane

CAS

33577-16-1

Formula

C3H8OS2

Molecular Weight

124.22

EINECS

251-577-2

Beilstein/Gmelin

906789

Physical and Chemical Properties

Appearance

Colorless to yellow liquid. With a stench.

Solubility in water

Very soluble

Melting Point

4 - 6

Boiling Point

258

Vapor Pressure

0.023 (25 C)

Density

1.19866 - 1.21618 g/cm3 (45 - 25 C)

Partition Coefficient

-.61

Heat Of Vaporization

47.5 kJ/mol

Vapor Density

4.28

Refractive Index

1.55 (20 C)

First Aid Measures

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use and store under nitrogen. Use only in a chemical fume hood. Keep from contact with moist air and steam. Do not breathe vapors.

Hazards Identification

Ingestion

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause nausea, headache, and vomiting.

Inhalation

May cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated. May cause nausea, headache, and vomiting.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

EC Safety Phrase

S 23 24/25

UN (DOT)

3334

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Fire Fighting Measures

Flash Point

121

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use carbon dioxide, dry chemical powder or appropriate foam.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Absorb spill using an absorbent, non-combustible material such as earth, sand, or vermiculite. Provide ventilation.

Stability and Reactivity

Disposal Code

6

Incompatibilities

Moisture, strong acids, strong oxidizing agents.

Stability

Stable under normal temperatures and pressures.

Decomposition

Carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen sulfide.

Transport Information

UN Number

3334

HS Code

2930 90 70