Product Identification

Product Name

Methyl anthranilate

Synonyms

Methyl 2-aminobenzoate
Nevoli oil

CAS

134-20-3

Formula

C8H9NO2

Molecular Weight

151.16999999999999

EINECS

205-132-4

RTECS

CB3325000

RTECS Class

Mutagen; Reproductive Effector; Natural Product; Primary Irritant

Merck

12,6099

Beilstein/Gmelin

606965

Beilstein Reference

4-14-00-01008

Physical and Chemical Properties

Appearance

Clear colorless to tan liquid with an odor of grapes. Has light blue fluorescence.

Solubility in water

Insoluble

Melting Point

24

Boiling Point

237

Vapor Pressure

0.02 (25 C)

Density

1.168 g/cm3 (15 C)

pKa/pKb

11.78 (pKb)

Partition Coefficient

2.04

Heat Of Vaporization

49.4 kJ/mol

Usage

As perfume for ointments, manufacture synthetic perfumes.

Refractive Index

1.583 (20 C)

First Aid Measures

Ingestion

Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids.

Handling and Storage

Storage

Store in a cool, dry place. Keep container closed when not in use.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

See inhalation.

Inhalation

This compound is an irritant to the skin.

Skin

See inhalation.

Eyes

See inhalation

EC Risk Phrase

R 36/38

EC Safety Phrase

S 26 36

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear safety glasses and chemical goggles if splashing is possible. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.

Poison Class

4

Fire Fighting Measures

Flash Point

104

Autoignition

530

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Upper exp. limit

7.8

Lower exp. limit

1.4

Fire Potential

This chemical is combustible.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Disposal Code

5

Incompatibilities

Acids - acid chlorides - acid anhydrides - chloroformates - strong oxidizing agents - strong bases - light.

Stability

Stable under normal temperatures and pressures.

Decomposition

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Transport Information

HS Code

2922 49 95