Product Identification

Product Name

1,3-Dinitro-2-chloro-5-trifluoromethylbenzene

Synonyms

2-Chloro-1,3-dinitro-5-(trifluoromethyl)benzene
3,5-Dinitro-4-chloro-alpha,alpha,alpha-trifluorotoluene
4-Chloro-3,5-dinitro-alpha,alpha,alpha-trifluorotoluene
Benzotrifluoride, 4-chloro-3,5-dinitro
Toluene, 4-chloro-3,5-dinitro-alpha,alpha,alpha-trifluoro

CAS

393-75-9

Formula

C7H2ClF3N2O4

Molecular Weight

270.55

EINECS

206-889-3

RTECS

XS9065000

RTECS Class

Other

Beilstein/Gmelin

1220937

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

Yellow crystals.

Solubility in water

Insoluble

Melting Point

56 - 58

Boiling Point

250

Vapor Pressure

0.007 (25 C)

Partition Coefficient

3.43

Heat Of Vaporization

49.7 kJ/mol

Usage

Intermediate in synthesis of herbicide trifluralin.

First Aid Measures

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation.

Hazards Identification

Inhalation

Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. Can produce delayed pulmonary edema.

Skin

Causes skin irritation. May be fatal if absorbed through the skin. May be harmful if absorbed through the skin.

Eyes

Causes eye irritation. May cause chemical conjunctivitis.

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause methemoglobinemia, cyanosis, convulsions, and death. May be harmful if swallowed.

EC Risk Phrase

R 20/22 24 36/37/38

EC Safety Phrase

S 26 28 36/37/39 45

UN (DOT)

2811

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed.

Fire Fighting Measures

Flash Point

122

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use agent most appropriate to extinguish fire. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Incompatibilities

Oxidizing agents, strong bases.

Stability

Stable at room temperature in closed containers under normal storage and handling conditions.

Decomposition

Hydrogen chloride, nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, hydrogen fluoride, nitrogen.

Transport Information

UN Number

2811

HS Code

2904 90 85