Product Identification

Product Name

Bis(2,4-pentanediono)nickel

Synonyms

Bis(2,4-pentanedionato)nickel
Bis(acetylacetonate)nickel
Nickel bis(2,4-pentanedionate)
Nickel bis(acetylacetonate)
Nickel, bis(2,4-pentanedionato-kO,kO')-, (SP-4-1)-
Nickelous acetylacetonate

CAS

3264-82-2

Formula

C10H14NiO4

Molecular Weight

256.91000000000003

EINECS

221-875-7

RTECS

SA2100000

RTECS Class

Other

Merck

12,6584

Beilstein/Gmelin

4157970

EC Class

harmful, sensitizing

Physical and Chemical Properties

Appearance

Light green solid.

Solubility in water

4.8 g/L (20 C)

Boiling Point

220

Vapor Pressure

20 (110 C)

Density

1.455 g/cm3 (20 C)

Usage

This material is used as a catalyst.

First Aid Measures

Ingestion

Never give anything by mouth to an unconscious person. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid immediately. Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well ventilated area. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Keep from contact with moist air and steam. Do not breathe dust.

Hazards Identification

Inhalation

May cause allergic respiratory reaction. Inhalation of high concentrations may cause coughing and shortness of breath. Can produce delayed pulmonary edema.

Skin

May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe dermatitis and urticaria(hives).

Eyes

May cause eye irritation.

Ingestion

May cause irritation of the digestive tract. May cause central nervous system effects.

EC Risk Phrase

R 45 20/21/22 43

EC Safety Phrase

S 53 45

UN (DOT)

3282

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Exposure Effects

May cause cancer according to animal studies. Prolonged or repeated exposure may cause lung irritation, chest pain, and pulmonary edema. May cause reproductive effects.

Exposure limit(s)

0.1 mg/m3 TLV

Poison Class

2

Fire Fighting Measures

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Sweep up, then place into a suitable container for disposal. Provide ventilation.

Stability and Reactivity

Disposal Code

15

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, moisture.

Decomposition

Carbon monoxide, carbon dioxide, 2,4-pentanedione, nickel oxide, acrid smoke and fumes, nickel.

Transport Information

UN Number

3282

HS Code

2942 00 00