Product Identification

Product Name

Ferrocene

Synonyms

(RS)-3-Hydroxytetrahydrofuran
3-Hydroxyoxolane
3-Hydroxytetrahydrofuran
bis(Cyclopentadienyl)iron
Ferrocene
Iron dicyclopentadienyl
Oxolan-3-ol

CAS

102-54-5

CAS

453-20-3

Formula

C10H10Fe

Formula

C4H8O2

Molecular Weight

186.04

Molecular Weight

88.1

EINECS

203-039-3

EINECS

207-219-2

RTECS

LK0700000

RTECS

LU3450050

RTECS Class

Tumorigen; Organometallic; Mutagen

RTECS Class

Drug

Merck

13,4070

Beilstein/Gmelin

102545

Beilstein/Gmelin

3385 (G)

Beilstein Reference

5-17-03-00010

EC Class

harmful, dangerous for the environment

Physical and Chemical Properties

Appearance

Clear light yellow.

Appearance

Orange crystalline solid with a camphor-like odor.

Solubility in water

Very soluble

Solubility in water

Insoluble

Boiling Point

170 - 173

Boiling Point

181

Vapor Pressure

0.03 (25 C)

Density

1.107 g/cm3 (0 C)

Density

1.490 g/cm3 (20 C)

Usage

Antiknock additive for gasoline, catalyst.

Refractive Index

1.4465 (20 C)

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.

Inhalation

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry place. Keep container closed when not in use.

Storage

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Handling

Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Hazards Identification

Inhalation

The toxicological properties of this substance have not been fully investigated. Inhalation of dust may cause respiratory tract irritation.

Skin

No information regarding skin irritation and other potential effects was found.

Eyes

No information regarding eye irritation and other potential effects was found.

Ingestion

May cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated. May cause blood abnormalities and hepatic cirrhosis.

EC Risk Phrase

R 22 51/53

EC Safety Phrase

S 22 36/37 61

UN (DOT)

3077

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Personal Protection

Eyes: Wear chemical goggles. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Respirators

A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use.

Exposure Effects

Blood pressure may be decreased following an iron overdose. Lethargy, restlessness or confusion may be seen early in the poisoning. Convulsions and coma may occur in later phases. Case reports of pregnant women who have received early aggressive treatment (decontamination and/or deferoxamine) have described good fetal outcomes.

Exposure Effects

The toxicological properties of this material have not been investigated.

Exposure limit(s)

NIOSH REL: TWA 10 mg/m3 (total) TWA 5 mg/m3 (resp) OSHA PEL: TWA 15 mg/m3 (total) TWA 5 mg/m3 (resp)

Fire Fighting Measures

Flash Point

81

Autoignition

> 150

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Extinguishing media: Use agent most appropriate to extinguish fire.

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment.

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

15

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents, ammonium perchlorate, tetranitromethane, mercury (III) nitrate

Decomposition

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Decomposition

Irritating and toxic fumes and gases.

Transport Information

UN Number

3077

HS Code

2931 00 95