Product Identification

Product Name

Sodium thiomethoxide

Synonyms

Sodium thiomethoxide
Sodium thiomethylate

CAS

5188-07-8

Formula

CH3NaS

EINECS

225-969-9

Merck

13,5983

Beilstein/Gmelin

3592983

Beilstein Reference

3-01-00-01212

Physical and Chemical Properties

Density

1.100 g/cm3 (20 C)

First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush with running water for at least 20 minutes. Wash skin with soap and water.

Eyes

In case of contact with substance, immediately flush with running water for at least 20 minutes.

Hazards Identification

Ingestion

May cause toxic effects.

Inhalation

Vapors may cause dizziness or suffocation. May cause toxic effects.

Skin

Contact with substance may cause severe burns.

Eyes

See Skin.

Hazards

Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers.

EC Risk Phrase

R 10 22 35

EC Safety Phrase

S 16 26 36/37/39 45

UN (DOT)

2920

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Fire Fighting Measures

Flash Point

27

Fire Fighting

Small Fires: Dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam.

Fire Potential

Flammable/combustible material. May be ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

Make no contact with the spilled material. Fully encapsulating, vapor protective clothing should be worn for spills and leaks with no fire. ELIMINATE all ignition sources and ground all equipment. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

Transport Information

UN Number

2920

Stability and Reactivity

Combustion Products

Fire will produce irritating, corrosive and/or toxic gases.