Product Identification

Product Name

Hexamethylene bis(chloroformate)

Synonyms

1,6-Bis[(chlorocarbonyl)oxy]hexane
1,6-Hexanediyl bis(chloroformate)
6-Carbonochloridoyloxyhexyl chloroformate
Carbonochloridic acid, 1,6-hexanediyl ester
Formic acid, chloro-, hexamethylene ester

CAS

2916-20-3

Formula

C8H12Cl2O4

Molecular Weight

243.09

EINECS

220-840-3

Beilstein/Gmelin

1783923

Beilstein Reference

4-03-00-00030

Physical and Chemical Properties

Solubility in water

Insoluble

Boiling Point

108 - 110 (0.6 torr)

Refractive Index

1.4518 (25 C)

First Aid Measures

Ingestion

Seek medical assistance.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.

Eyes

Immediately flush with running water for at least 20 minutes.

Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Ingestion

See Inhalation.

Inhalation

TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns, or death. Effects may be delayed.

Skin

See Inhalation.

Eyes

See Inhalation.

Hazards

Vapors form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff.

UN (DOT)

2742

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Poison Class

2

Fire Fighting Measures

Fire Fighting

Note: Most foams will react with the material and release corrosive/toxic gases. Small Fires: carbon dioxide, dry chemical, dry sand, alcohol-resistant foam. Large Fires: Water spray, fog or alcohol-resistant foam.

Fire Potential

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

ELIMINATE all ignition sources and groumd all equipment used when handling the product. Do not touch spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. FOR CHLOROSILANES, use AFFF alcohol-resistant medium expansion foam to reduce vapors. DO NOT GET WATER on spilled substance or inside containers. Cover with DRY earth, DRY sand, or other non-combustible material followed with plastic sheet to minimize spreading or contact with rain. Use clean non-sparking tools to collect material and place it into loosley covered plastic containers for later disposal.

Stability and Reactivity

Stability

No data.

Combustion Products

Fire will produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2742

Hazard Class

6.1

Packing Group

I