Product Identification

Product Name

3-Bromobiphenyl

Synonyms

[1,1'-Biphenyl]-3-yl bromide
1-Bromo-3-phenylbenzene
3-Bromo-1,1'-biphenyl
3-Xenyl bromide
m-Bromobiphenyl

CAS

2113-57-7

Formula

C12H9Br

Molecular Weight

233.1

EINECS

218-304-9

RTECS

DV1750000

RTECS Class

Other

Beilstein/Gmelin

2043191

Beilstein Reference

4-05-00-01818

Physical and Chemical Properties

Appearance

Clear yellow viscous liquid.

Solubility in water

Insoluble

Melting Point

9

Boiling Point

299

Vapor Pressure

0.002 (25 C)

Density

1.41 g/cm3 (20 C)

Partition Coefficient

4.72

Heat Of Vaporization

51.8 kJ/mol

Refractive Index

1.6411 (20 C)

First Aid Measures

Ingestion

Get medical aid. Wash mouth out with water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Store in a tightly closed container.

Handling

Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.

Hazards Identification

Inhalation

Causes respiratory tract irritation. May be harmful if inhaled.

Skin

Causes skin irritation. May be harmful if absorbed through the skin.

Eyes

Causes eye irritation.

Ingestion

May cause irritation of the digestive tract. May be harmful if swallowed.

Hazards

Containers may explode when heated.

EC Safety Phrase

S 24/25

UN (DOT)

2315

Exposure Controls/Personal Protection

Personal Protection

Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Exposure Effects

The toxological properties of this substance have not been fully investigated.

Poison Class

4

Fire Fighting Measures

Flash Point

136

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Fire Potential

This material is probably combustible.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container.

Stability and Reactivity

Stability

No data.

Incompatibilities

Strong oxidizing agents.

Decomposition

Carbon monoxide, carbon dioxide, hydrogen bromide.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2315

Hazard Class

9

Packing Group

II