Product Identification

Product Name

Succinbromimide

Synonyms

1-Bromo-2,5-pyrrolidinedione
1-Bromopyrrolidine-2,5-dione

CAS

128-08-5

Formula

C4H4BrNO2

Molecular Weight

177.99

EINECS

204-877-2

RTECS

WN2275000

Merck

13,1423

Beilstein/Gmelin

113916

Beilstein Reference

5-21-09-00543

EC Class

harmful, irritant

Physical and Chemical Properties

Appearance

White to pale yellow solid with a faint promine odor.

Solubility in water

15 g/L

Melting Point

174 - 179

Boiling Point

339

Vapor Pressure

11

Density

2.098 g/cm3

Partition Coefficient

.04

Usage

Substance is used in bromination of olefins.

Vapor Density

6.1

First Aid Measures

Ingestion

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container. Keep away from water.

Handling

Wash thoroughly after handling. Use only in a well ventilated area. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.

Inhalation

May cause irritation of the respiratory tract with burning pain in the nose and throat, coughing, wheezing, shortness of breath and pulmonary edema. May cause effects similar to those described for ingestion.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

EC Risk Phrase

R 22 34

EC Safety Phrase

S 26 36/37/39 45

UN (DOT)

3261

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Poison Class

2

Fire Fighting Measures

Flash Point

180

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Vacuum or sweep up material and place into a suitable disposal container. Wash area with soap and water. Avoid generating dusty conditions. Provide ventilation.

Stability and Reactivity

Disposal Code

24

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents; strong acids; strong bases; iron and iron salts; aniline; diallylsulfide; hydrazine hydrate; propionitrile; dibenzoyl peroxide + 4-toluic acid.

Decomposition

Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.

Transport Information

UN Number

3261

HS Code

2925 19 95