Product Identification

Product Name

Pine needle oil

Synonyms

Oils, pine
Terpineols
Yarmor

CAS

8002-09-3

RTECS

TK5100000

RTECS Class

Agricultural Chemical and Pesticide; Human Data; Primary Irritant

Beilstein/Gmelin

NA

Physical and Chemical Properties

Appearance

A clear colorless to light amber colored liquid. Primarily comprised of terpene alcohols.

Solubility in water

20 mg/L

Melting Point

0-10

Boiling Point

195

Density

0.95 g/cm3 (20 C)

Usage

Insecticide, microbiocide.

Vapor Density

5.3

First Aid Measures

Ingestion

Seek medical attention. If individual is drowsy or unconscious, do not give anything by mouth; place individual on the left side with the head down. Contact a physician, medical facility, or poison control center for advice about whether to induce vomiting. If possible, do not leave individual unattended.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. Wash skin with soap and water. Flush with running water for at least 20 minutes

Eyes

Flush with running water for at least 20 minutes.

Handling and Storage

Storage

Maintain in a cool, dry location in a sealed container.

Handling

Containers of this material may be hazardous when emptied. Since emptied containers retain product residues (vapor, liquid, and/or solid), all hazard precautions given in the data sheet must be observed.

Hazards Identification

Inhalation

Vapors may cause dizziness or suffocation. May cause irritation or burns.

Skin

May cause mild skin irritation. Symptoms may include redness and burning of skin.

Eyes

Can cause eye irritation. Symptoms include stinging, tearing, redness, and swelling of eyes.

Ingestion

Swallowing small amounts of this material during normal handling is not likely to cause harmful effects. Swallowing large amounts may be harmful. This material can get into the lungs during swallowing or vomiting. This results in lung inflammation and other lung injury.

Hazards

Forms heavy black smoke and soot.

UN (DOT)

1272

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Exposure Effects

Signs and symptoms of exposure to this material through breathing, swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset (nausea, vomiting, diarrhea) irritation (nose, throat, airways), central nervous system depression (dizziness, drowsiness, weakness, fatigue, nausea, headache, unconsciousness).

Poison Class

4

Fire Fighting Measures

Flash Point

65

Fire Fighting

Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog. Solid streams of water may be ineffective. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide.

Fire Potential

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames.

Accidental Release Measures

Small spills/leaks

Make no contact with the spilled material. ELIMINATE all ignition sources and ground all equipment. Stop leak if you can do it without risk. A vapor suppressing foam may be used to reduce vapors. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Use clean non-sparking tools to collect absorbed material.

Stability and Reactivity

Incompatibilities

Flammable and/or toxic gases are generated by combination with with alkali metals, nitrides, and strong reducing agents Reacts with oxoacids and carboxylic acids to form esters plus water Incompatible with oxidizing agents.

Stability

Stable at room temperature in closed containers under normal storage and handling conditions.

Decomposition

Carbon dioxide and carbon monoxide, various hydrocarbons.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

1272

Hazard Class

3

Packing Group

III