Product Identification

Product Name

2-Furyl methyl ketone

Synonyms

1-(2-Furanyl)ethanone
1-Furan-2-ylethanone
2-Acetylfuran
2-Furyl methyl ketone
Methyl 2-furyl ketone

CAS

1192-62-7

Formula

C6H6O2

Molecular Weight

110.11

EINECS

214-757-1

RTECS

OB3870000

RTECS Class

Mutagen

Beilstein/Gmelin

107909

Beilstein Reference

5-17-09-00381

EC Class

toxic, irritant

Physical and Chemical Properties

Appearance

Colorless or yellow or brown solid.

Solubility in water

Soluble

Melting Point

29 - 33

Boiling Point

183

Vapor Pressure

0.8 (25 C)

Density

1.098 g/cm3 (20 C)

Partition Coefficient

.46

Heat Of Vaporization

42.00 kJ/mol

Refractive Index

1.5015 (20 C)

First Aid Measures

Ingestion

Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

Skin

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Handling and Storage

Storage

Store in a cool, dry place. Keep container closed when not in use. Refrigerator (approx 4 C).

Handling

Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

Ingestion of large amounts may cause gastrointestinal irritation.

Inhalation

May cause respiratory tract irritation.

Skin

May cause skin irritation.

Eyes

May cause eye irritation.

EC Risk Phrase

R 21 23/25 36/38

EC Safety Phrase

S 23 36/37/39 45

UN (DOT)

2811

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

71

Autoignition

370

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam.

Upper exp. limit

15.2

Lower exp. limit

2.1

Accidental Release Measures

Small spills/leaks

Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal.

Stability and Reactivity

Disposal Code

3

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents; strong bases; and strong reducing agents.

Decomposition

Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.

Transport Information

UN Number

2811

HS Code

2932 19 00