Product Identification

Product Name

1,4-Diiodobutane

Synonyms

1,4-Diodobutane
Tetramethylene diiodide

CAS

628-21-7

Formula

C4H8I2

Molecular Weight

309.91000000000003

EINECS

211-032-1

RTECS

EJ9200000

RTECS Class

Mutagen

Beilstein/Gmelin

1098276

Beilstein Reference

4-01-00-00276

EC Class

irritant

Physical and Chemical Properties

Appearance

Clear slight brown liquid. Sharp odor.

Solubility in water

Insoluble

Melting Point

5.8

Boiling Point

247

Vapor Pressure

0.04 (25 C)

Density

2.3659 g/cm3 (15 C)

Partition Coefficient

3.45

Heat Of Vaporization

46.4 kJ/mol

Heat Of Combustion

-2687 kJ/mol

Refractive Index

1.6155 (20 C)

First Aid Measures

Ingestion

Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.

Inhalation

Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.

Skin

Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.

Eyes

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.

Handling and Storage

Storage

Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.

Handling

Wash thoroughly after handling. Wash hands before eating. Use with adequate ventilation. Avoid breathing dust, vapor, mist, or gas. Do not get on skin or in eyes. Avoid ingestion and inhalation.

Hazards Identification

Ingestion

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.

Inhalation

Causes respiratory tract irritation.

Skin

Causes skin irritation.

Eyes

Causes eye irritation.

EC Risk Phrase

R 36/38

EC Safety Phrase

S 26 36

Exposure Controls/Personal Protection

Personal Protection

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Respirators

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Fire Fighting Measures

Flash Point

117

Fire Fighting

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. To extinguish fire use water spray, dry chemical, carbon dioxide, or chemical foam.

Accidental Release Measures

Small spills/leaks

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Clean up spills immediately, using the appropriate protective equipment.

Stability and Reactivity

Stability

Stable under normal temperatures and pressures.

Incompatibilities

Strong oxidizing agents and strong bases.

Decomposition

Carbon monoxide, carbon dioxide, hydrogen iodide.

Transport Information

HS Code

2903 30 80