Product Identification

Product Name

Dicopper chloride trihydroxide

Synonyms

Aviocaffaro
Basic copper chloride
Chempar
Copper chloride hydroxide
Coppercide
Copperthom

CAS

1332-65-6

Formula

Cl2Cu4H3O3

Molecular Weight

213.57

EINECS

215-572-9

Beilstein/Gmelin

168034 (G)

Physical and Chemical Properties

Appearance

Green, orthorhombic crystals.

Solubility in water

practically insoluble

Density

3.76-3.78 g/cm3 (20 C)

Usage

Bird repellent, fungicide.

First Aid Measures

Ingestion

Following ingestion and/or prior to gastric evacuation, immediately dilute with 4 to 8 ounces (120 to 240 ml) of milk or water (not to exceed 15 ml/kg in a child). Vomiting is rapid and spontaneous in most patients following ingestion of copper salts. Ipecac is contraindicated after ingestion of caustic copper salts because of the risk of further injury to the gastrointestinal mucosa and the possibility of severe cns changes.

Inhalation

Move victim to fresh air. Apply artificial respiration if victim is not breathing. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Administer oxygen if breathing is difficult.

Skin

Remove and isolate contaminated clothing and shoes. Remove material from skin immediately. Immediately flush with running water for at least 20 minutes. For minor skin contact, avoid spreading material on unaffected skin.

Eyes

Immediately flush with running water for at least 20 minutes.

Handling and Storage

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

Hazards Identification

Inhalation

Metal fume fever, wheezing and rales have been reported in workers exposed to fine copper dust. Dyspnea has developed after oral copper exposure. Pulmonary edema and alveolar inflammation have been noted in animals.

Skin

Skin exposure can produce in severe irritation, itching, erythema, dermatitis and eczema; systemic toxicity may result.

Eyes

See Inhalation.

Ingestion

Gastroenteritis with vomiting may occur after ingestion of some copper salts. Mucosal erosions, a metallic taste, burning epigastric sensation and diarrhea may also occur.

UN (DOT)

2775

Exposure Controls/Personal Protection

Personal Protection

Wear appropriate protective gloves, clothing and goggles.

Respirators

Wear positive pressure self-contained breathing apparatus (SCBA).

Exposure Effects

Increased temperature may be noted in some cases. Abnormally low blood pressure may occur. Mental status may be depressed.

Fire Fighting Measures

Fire Fighting

Use method most appropriate to fight surrounding fire.

Fire Potential

Non-Combustible

Accidental Release Measures

Small spills/leaks

Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if you can do it without risk. Cover with plastic sheet to prevent spreading. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. DO NOT GET WATER INSIDE CONTAINERS.

Stability and Reactivity

Stability

No data.

Combustion Products

Fire may produce irritating, corrosive and/or toxic gases.

Transport Information

UN Number

2775

Hazard Class

6.1

Packing Group

I; II; III